Well-defined mono(η3-allyl)nickel complex ≡MONi(η3-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

Lidong Li; Edy Abou-Hamad; Dalaver H. Anjum; Lu Zhou; Paco V. Laveille; Lyndon Emsley; Jean Marie Basset

doi:10.1039/c4cc02962c

Well-defined mono(η³-allyl)nickel complex ≡MONi(η³-C₃H₅) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

Lidong Li, Edy Abou-Hamad, Dalaver H. Anjum, Lu Zhou, Paco V. Laveille, Lyndon Emsley, Jean Marie Basset

Physics

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1–3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(η³-allyl)nickel complexes ≡MONi(η³-C₃H₅) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR.

Original language	British English
Pages (from-to)	7716-7719
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	57
DOIs	https://doi.org/10.1039/c4cc02962c
State	Published - 19 Jun 2014

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Li, L., Abou-Hamad, E., Anjum, D. H., Zhou, L., Laveille, P. V., Emsley, L., & Basset, J. M. (2014). Well-defined mono(η³-allyl)nickel complex ≡MONi(η³-C₃H₅) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles. Chemical Communications, 50(57), 7716-7719. https://doi.org/10.1039/c4cc02962c

@article{f20f43eb5f394e939f09a599bf91161d,

title = "Well-defined mono(η3-allyl)nickel complex ≡MONi(η3-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles",

abstract = "Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1–3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(η3-allyl)nickel complexes ≡MONi(η3-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR.",

author = "Lidong Li and Edy Abou-Hamad and Anjum, {Dalaver H.} and Lu Zhou and Laveille, {Paco V.} and Lyndon Emsley and Basset, {Jean Marie}",

year = "2014",

month = jun,

day = "19",

doi = "10.1039/c4cc02962c",

language = "British English",

volume = "50",

pages = "7716--7719",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "57",

}

Li, L, Abou-Hamad, E, Anjum, DH, Zhou, L, Laveille, PV, Emsley, L & Basset, JM 2014, 'Well-defined mono(η³-allyl)nickel complex ≡MONi(η³-C₃H₅) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles', Chemical Communications, vol. 50, no. 57, pp. 7716-7719. https://doi.org/10.1039/c4cc02962c

Well-defined mono(η³-allyl)nickel complex ≡MONi(η³-C₃H₅) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles. / Li, Lidong; Abou-Hamad, Edy; Anjum, Dalaver H. et al.
In: Chemical Communications, Vol. 50, No. 57, 19.06.2014, p. 7716-7719.

Research output: Contribution to journal › Article › peer-review

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T1 - Well-defined mono(η3-allyl)nickel complex ≡MONi(η3-C3H5) (M = Si or Al) grafted onto silica or alumina

T2 - a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

AU - Li, Lidong

AU - Abou-Hamad, Edy

AU - Anjum, Dalaver H.

AU - Zhou, Lu

AU - Laveille, Paco V.

AU - Emsley, Lyndon

AU - Basset, Jean Marie

PY - 2014/6/19

Y1 - 2014/6/19

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AB - Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1–3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(η3-allyl)nickel complexes ≡MONi(η3-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR.

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