@article{3b5e32a3a982435b982f7cb5b3e66787,
title = "Vapor Liquid Equilibria of Binary Mixtures of 1-Butyl-3-methylimidazolium Triflate (C4mimTfO) and Molecular Solvents: N-Alkyl Alcohols and Water",
abstract = "Isobaric vapor liquid equilibria (VLE) of binary mixtures of the ionic liquid (IL) 1-butyl-3-methylimidazolium trifluoromethanesulfonate (C4mimTfO) with either water or short chained n-alkyl alcohols (methanol, ethanol, propan-1-ol, and butan-1-ol) are described in this study. Two different microebulliometers and a classical VLE apparatus were compared and the VLEs were determined in the composition range 0.4 ≤ x(solvent) ≤ 1 at three different pressure levels (p = 500 mbar, 700 mbar, and 1000 mbar). The experimental data were modeled using the soft-SAFT equation of state, which was able to accurately describe the nonideal behavior of these mixtures. The combined experimental-modeling results obtained contribute to establish the structure-property relationship between the C4mimTfO and n-alkyl alcohol molecules and to infer about its influence on the phase behavior of these solvents.",
author = "Marcus Stuckenholz and Crespo, \{Emanuel A.\} and Vega, \{Lourdes F.\} and Carvalho, \{Pedro J.\} and Coutinho, \{Jo{\~a}o A.P.\} and Wolffram Schr{\"o}er and Johannes Kiefer and Bernd Rathke",
note = "Funding Information: The authors gratefully acknowledge financial support by Forschungsf{\"o}rderung Universitaẗ Bremen and by the STSM of M. Stuckenholz within the COST action CM1206-30741, EXIL - Exchange on Ionic Liquids. This work was developed in the scope of the project CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (ref. FCT UID/CTM/50011/ 2013), funded by FEDER through COMPETE2020 - Programa Operacional Competitividade e Internacionalizac{\c a} {\~o} (POCI) and by national funds through FCT -Fundac{\c a} {\~o} para a Cienci{\^a} e a Tecnologia. P. J. Carvalho acknowledges FCT for a contract under the Investigador FCT 2015, Contract IF/00758/2015, and E. A. Crespo acknowledges Ph.D. Grant SFRH/BD/ 130870/2017. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = jun,
day = "7",
doi = "10.1021/acs.jpcb.8b03278",
language = "British English",
volume = "122",
pages = "6017--6032",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "22",
}