Vanadium oxide surfaces and supported vanadium oxide nanoparticles

S. Guimond; M. Abu Haija; S. Kaya; J. Lua; J. Weissenrieder; S. Shaikhutdinov; H. Kuhlenbeck; H. J. Freund; J. Döbler; J. Sauer

doi:10.1007/s11244-006-0076-8

Vanadium oxide surfaces and supported vanadium oxide nanoparticles

S. Guimond, M. Abu Haija, S. Kaya, J. Lua, J. Weissenrieder, S. Shaikhutdinov, H. Kuhlenbeck, H. J. Freund, J. Döbler, J. Sauer

Chemistry

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79 Scopus citations

Abstract

The information obtained from the characterization of vanadium oxide single crystal surfaces is related to the study of vanadia nanoparticles supported on silica and alumina thin films, model systems for the so-called ''supported monolayer vanadia catalysts''. It is found that these particles have properties similar to V₂O₃ surfaces, where the topmost V ions are involved in vanadyl groups and have a 5+ oxidation state. A vibrational spectroscopy investigation combined with DFT calculations show that the accepted interpretation of vibrational spectra from vanadia catalysts must be revised.

Original language	British English
Pages (from-to)	117-125
Number of pages	9
Journal	Topics in Catalysis
Volume	38
Issue number	1-3
DOIs	https://doi.org/10.1007/s11244-006-0076-8
State	Published - Jul 2006

Keywords

Alumina
Dft calculation
Infrared (ir) spectroscopy
Photoelectron spectroscopy (pes)
Scanning tunneling microscopy (stm)
Silica
Vanadium oxide

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10.1007/s11244-006-0076-8

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title = "Vanadium oxide surfaces and supported vanadium oxide nanoparticles",

abstract = "The information obtained from the characterization of vanadium oxide single crystal surfaces is related to the study of vanadia nanoparticles supported on silica and alumina thin films, model systems for the so-called ''supported monolayer vanadia catalysts''. It is found that these particles have properties similar to V2O3 surfaces, where the topmost V ions are involved in vanadyl groups and have a 5+ oxidation state. A vibrational spectroscopy investigation combined with DFT calculations show that the accepted interpretation of vibrational spectra from vanadia catalysts must be revised.",

keywords = "Alumina, Dft calculation, Infrared (ir) spectroscopy, Photoelectron spectroscopy (pes), Scanning tunneling microscopy (stm), Silica, Vanadium oxide",

author = "S. Guimond and {Abu Haija}, M. and S. Kaya and J. Lua and J. Weissenrieder and S. Shaikhutdinov and H. Kuhlenbeck and Freund, {H. J.} and J. D{\"o}bler and J. Sauer",

note = "Funding Information: We are grateful to funding through Sonderfors-chungsbereich 546 and through the ATHENA project founded by the EPSRC. The {\textquoteleft}{\textquoteleft}Fonds der Chemischen Industrie{\textquoteright}{\textquoteright} is also gratefully acknowledged.",

year = "2006",

month = jul,

doi = "10.1007/s11244-006-0076-8",

language = "British English",

volume = "38",

pages = "117--125",

journal = "Topics in Catalysis",

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T1 - Vanadium oxide surfaces and supported vanadium oxide nanoparticles

AU - Guimond, S.

AU - Abu Haija, M.

AU - Kaya, S.

AU - Lua, J.

AU - Weissenrieder, J.

AU - Shaikhutdinov, S.

AU - Kuhlenbeck, H.

AU - Freund, H. J.

AU - Döbler, J.

AU - Sauer, J.

N1 - Funding Information: We are grateful to funding through Sonderfors-chungsbereich 546 and through the ATHENA project founded by the EPSRC. The ‘‘Fonds der Chemischen Industrie’’ is also gratefully acknowledged.

PY - 2006/7

Y1 - 2006/7

N2 - The information obtained from the characterization of vanadium oxide single crystal surfaces is related to the study of vanadia nanoparticles supported on silica and alumina thin films, model systems for the so-called ''supported monolayer vanadia catalysts''. It is found that these particles have properties similar to V2O3 surfaces, where the topmost V ions are involved in vanadyl groups and have a 5+ oxidation state. A vibrational spectroscopy investigation combined with DFT calculations show that the accepted interpretation of vibrational spectra from vanadia catalysts must be revised.

AB - The information obtained from the characterization of vanadium oxide single crystal surfaces is related to the study of vanadia nanoparticles supported on silica and alumina thin films, model systems for the so-called ''supported monolayer vanadia catalysts''. It is found that these particles have properties similar to V2O3 surfaces, where the topmost V ions are involved in vanadyl groups and have a 5+ oxidation state. A vibrational spectroscopy investigation combined with DFT calculations show that the accepted interpretation of vibrational spectra from vanadia catalysts must be revised.

KW - Alumina

KW - Dft calculation

KW - Infrared (ir) spectroscopy

KW - Photoelectron spectroscopy (pes)

KW - Scanning tunneling microscopy (stm)

KW - Silica

KW - Vanadium oxide

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U2 - 10.1007/s11244-006-0076-8

DO - 10.1007/s11244-006-0076-8

M3 - Article

AN - SCOPUS:33749065418

SN - 1022-5528

VL - 38

SP - 117

EP - 125

JO - Topics in Catalysis

JF - Topics in Catalysis

IS - 1-3

ER -

Vanadium oxide surfaces and supported vanadium oxide nanoparticles

Abstract

Keywords

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