Tribological performance comparing different refrigerant-lubricant systems: The case of environmentally friendly HFO-1234yf refrigerant

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Abstract

We report on the tribological performance of gray cast iron with different lubricants, namely PAG (Polyalkylene glycol), POE (Polyolester), and Mineral oil, in the presence of environmentally friendly HFO-1234yf refrigerant. Two operating temperatures (24 °C and 110 °C) were used to investigate the mutual solubility of lubricant/refrigerant systems. PAG/HFO-1234yf exhibited better tribological performance compared to the other systems. The better performance was attributed to lower solubility of PAG in HFO-1234yf refrigerant, thus allowing the lubricant and refrigerant to preserve their unique properties. Using Scanning Electron Microscopy, plastic flow associated with adhesive wear was revealed for PAG/HFO-1234yf, where an anti-wear film over the surface was also identified. X-ray Photoelectron Spectroscopy identified a fluorine enriched protective layer in the case of PAG/HFO-1234yf at 110 °C.

Original languageBritish English
Pages (from-to)176-186
Number of pages11
JournalTribology International
Volume78
DOIs
StatePublished - Oct 2014

Keywords

  • Compressor
  • Environmentally friendly refrigerant
  • HFO-1234yf
  • Scuffing

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