Transition of crystalline orientation of yttria-stabilized zirconia films grown by pulsed laser deposition

X. Zhang; P. Berdahl; A. Klini; C. Fotakis; S. S. Mao

doi:10.1007/s00339-008-4475-5

Transition of crystalline orientation of yttria-stabilized zirconia films grown by pulsed laser deposition

X. Zhang
, P. Berdahl
, A. Klini
, C. Fotakis
, S. S. Mao

Mechanical & Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

We have synthesized 5 wt.∈%-yttria-stabilized zirconia (YSZ) films on stainless steel and glass substrates by pulsed laser deposition (PLD) at substrate temperatures between 60 and 600 °C and oxygen pressures from 0.1 to 1000 mTorr. While highly (101)-oriented tetragonal YSZ films are obtained at intermediate oxygen pressures, near complete (001)-oriented tetragonal films are achieved at lower oxygen pressures, with a full width at half maximum X-ray peak of only 0.4°. The results can be attributed to surface energy-induced orientation; that is, the lowest surface energy plane of the YSZ films changes from (101) plane at intermediate pressures to the (001) plane at lower oxygen pressures due to surface relaxation.

Original language	British English
Pages (from-to)	407-410
Number of pages	4
Journal	Applied Physics A: Materials Science and Processing
Volume	91
Issue number	3
DOIs	https://doi.org/10.1007/s00339-008-4475-5
State	Published - Jun 2008

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title = "Transition of crystalline orientation of yttria-stabilized zirconia films grown by pulsed laser deposition",

abstract = "We have synthesized 5 wt.∈\%-yttria-stabilized zirconia (YSZ) films on stainless steel and glass substrates by pulsed laser deposition (PLD) at substrate temperatures between 60 and 600 °C and oxygen pressures from 0.1 to 1000 mTorr. While highly (101)-oriented tetragonal YSZ films are obtained at intermediate oxygen pressures, near complete (001)-oriented tetragonal films are achieved at lower oxygen pressures, with a full width at half maximum X-ray peak of only 0.4°. The results can be attributed to surface energy-induced orientation; that is, the lowest surface energy plane of the YSZ films changes from (101) plane at intermediate pressures to the (001) plane at lower oxygen pressures due to surface relaxation.",

author = "X. Zhang and P. Berdahl and A. Klini and C. Fotakis and Mao, \{S. S.\}",

year = "2008",

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T1 - Transition of crystalline orientation of yttria-stabilized zirconia films grown by pulsed laser deposition

AU - Zhang, X.

AU - Berdahl, P.

AU - Klini, A.

AU - Fotakis, C.

AU - Mao, S. S.

PY - 2008/6

Y1 - 2008/6

N2 - We have synthesized 5 wt.∈%-yttria-stabilized zirconia (YSZ) films on stainless steel and glass substrates by pulsed laser deposition (PLD) at substrate temperatures between 60 and 600 °C and oxygen pressures from 0.1 to 1000 mTorr. While highly (101)-oriented tetragonal YSZ films are obtained at intermediate oxygen pressures, near complete (001)-oriented tetragonal films are achieved at lower oxygen pressures, with a full width at half maximum X-ray peak of only 0.4°. The results can be attributed to surface energy-induced orientation; that is, the lowest surface energy plane of the YSZ films changes from (101) plane at intermediate pressures to the (001) plane at lower oxygen pressures due to surface relaxation.

AB - We have synthesized 5 wt.∈%-yttria-stabilized zirconia (YSZ) films on stainless steel and glass substrates by pulsed laser deposition (PLD) at substrate temperatures between 60 and 600 °C and oxygen pressures from 0.1 to 1000 mTorr. While highly (101)-oriented tetragonal YSZ films are obtained at intermediate oxygen pressures, near complete (001)-oriented tetragonal films are achieved at lower oxygen pressures, with a full width at half maximum X-ray peak of only 0.4°. The results can be attributed to surface energy-induced orientation; that is, the lowest surface energy plane of the YSZ films changes from (101) plane at intermediate pressures to the (001) plane at lower oxygen pressures due to surface relaxation.

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M3 - Article

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SN - 0947-8396

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SP - 407

EP - 410

JO - Applied Physics A: Materials Science and Processing

JF - Applied Physics A: Materials Science and Processing

IS - 3

ER -

Transition of crystalline orientation of yttria-stabilized zirconia films grown by pulsed laser deposition

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