Transition-Metal-Catalyzed Directed C−H Functionalization in/on Water

Tariq A. Shah; Tanumay Sarkar; Subhradeep Kar; Prabhat Kumar Maharana; Kangkan Talukdar; Tharmalingam Punniyamurthy

doi:10.1002/asia.202300815

Transition-Metal-Catalyzed Directed C−H Functionalization in/on Water

Tariq A. Shah
, Tanumay Sarkar
, Subhradeep Kar
, Prabhat Kumar Maharana
, Kangkan Talukdar
, Tharmalingam Punniyamurthy

Indian Institute of Technology Guwahati

Research output: Contribution to journal › Review article › peer-review

17 Scopus citations

Abstract

Directing group assisted C−H bond functionalization using transition-metal-catalysis has emerged as a reliable synthetic tool for the construction of regioselective carbon-carbon/heteroatom bonds. Off late, “in/on water directed transition-metal-catalysis”, though still underdeveloped, has appeared as one of the prominent themes in sustainable organic chemistry. This article covers the advancements, mechanistic insights and application of the sustainable directed C−H bond functionalization of (hetero)arenes in/on water in the presence of transition-metal-catalysis.

Original language	British English
Article number	e202300815
Journal	Chemistry - An Asian Journal
Volume	19
Issue number	1
DOIs	https://doi.org/10.1002/asia.202300815
State	Published - 2 Jan 2024

Keywords

Directing group
reaction in/on water
Site-selective C−H Functionalization
transition-metal-catalysis

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10.1002/asia.202300815

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title = "Transition-Metal-Catalyzed Directed C−H Functionalization in/on Water",

abstract = "Directing group assisted C−H bond functionalization using transition-metal-catalysis has emerged as a reliable synthetic tool for the construction of regioselective carbon-carbon/heteroatom bonds. Off late, “in/on water directed transition-metal-catalysis”, though still underdeveloped, has appeared as one of the prominent themes in sustainable organic chemistry. This article covers the advancements, mechanistic insights and application of the sustainable directed C−H bond functionalization of (hetero)arenes in/on water in the presence of transition-metal-catalysis.",

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AU - Shah, Tariq A.

AU - Sarkar, Tanumay

AU - Kar, Subhradeep

AU - Maharana, Prabhat Kumar

AU - Talukdar, Kangkan

AU - Punniyamurthy, Tharmalingam

PY - 2024/1/2

Y1 - 2024/1/2

N2 - Directing group assisted C−H bond functionalization using transition-metal-catalysis has emerged as a reliable synthetic tool for the construction of regioselective carbon-carbon/heteroatom bonds. Off late, “in/on water directed transition-metal-catalysis”, though still underdeveloped, has appeared as one of the prominent themes in sustainable organic chemistry. This article covers the advancements, mechanistic insights and application of the sustainable directed C−H bond functionalization of (hetero)arenes in/on water in the presence of transition-metal-catalysis.

AB - Directing group assisted C−H bond functionalization using transition-metal-catalysis has emerged as a reliable synthetic tool for the construction of regioselective carbon-carbon/heteroatom bonds. Off late, “in/on water directed transition-metal-catalysis”, though still underdeveloped, has appeared as one of the prominent themes in sustainable organic chemistry. This article covers the advancements, mechanistic insights and application of the sustainable directed C−H bond functionalization of (hetero)arenes in/on water in the presence of transition-metal-catalysis.

KW - Directing group

KW - reaction in/on water

KW - Site-selective C−H Functionalization

KW - transition-metal-catalysis

UR - https://www.scopus.com/pages/publications/85175692241

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M3 - Review article

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JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

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ER -

Transition-Metal-Catalyzed Directed C−H Functionalization in/on Water

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Keywords

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