The effect of chloride ions on the passive films of titanium in sulfuric acids

Jing Liu, Akram Alfantazi, Edouard Asselin

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

4 Scopus citations

Abstract

The effect of chloride ions on the passivity of titanium in sulfuric acids was investigated by potentiodynamic and potentiostatic anodizing, Mott-Schottky analysis and the point defect model (PDM).The anodizing results indicated that chloride ions facilitate the anodic passivity of titanium in sulfuric acids.Based on the Mott-Schottky analysis in conjunction with the PDM, it was shown that the donor density decreases exponentially with increasing film formation potential. Also, the results indicated that with the increasing concentration of chloride ions, the donor density decreases,while the diffusivityof the donors increases at the same film formation potential.

Original languageBritish English
Title of host publicationCorrosion and Surface Engineering
EditorsJoanna Michalska, Maciej Sowa
Pages67-70
Number of pages4
ISBN (Electronic)9783038353911
DOIs
StatePublished - 2015
EventInternational Scientific Conference Corrosion, 2014 - Gliwice, Poland
Duration: 18 Nov 201421 Nov 2014

Publication series

NameSolid State Phenomena
Volume227
ISSN (Print)1012-0394
ISSN (Electronic)1662-9779

Conference

ConferenceInternational Scientific Conference Corrosion, 2014
Country/TerritoryPoland
CityGliwice
Period18/11/1421/11/14

Keywords

  • Chloride
  • Mott-schottky
  • Passive films
  • PDM
  • Titanium

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