TY - JOUR
T1 - Synthesis of carbon quantum dots via electrochemically-induced carbon dioxide nanobubbles exfoliation of graphite for heavy metal detection in wastewater
AU - Yat, Yu Dong
AU - Foo, Henry Chee Yew
AU - Tan, Inn Shi
AU - Lam, Man Kee
AU - Show, Pau Loke
AU - Ng, Bryant Wei Liang
N1 - Publisher Copyright:
© 2024 The Authors
PY - 2024/6
Y1 - 2024/6
N2 - Carbon quantum dots (CQDs) offer significant promise across industries due to their distinctive optical properties and strong biocompatibility. However, conventional synthesis methods frequently need more precision in controlling nanoparticle size, shape, and uniformity, limiting their versatility in diverse applications. Therefore, this study introduced an innovative approach to synthesising CQDs by combining electrochemical techniques with carbon dioxide (CO2) nanobubbles, circumventing the need for conventional surfactant-based exfoliation. According to the findings, the synthesised CQDs exhibited remarkable properties, including a high quantum yield of 26.17% and an average particle size of 2.24 ± 1.07 nm. Such characteristics render them exceptionally suitable for portable sensors for heavy metal detection in wastewater. Moreover, the investigation revealed the outstanding selectivity of the synthesised CQDs, particularly towards iron (Fe3+) ions, but demonstrated limited reactivity towards lead (Pb2+) and copper (Cu2+) ions. The novel approach also generated non-toxic CQD under the supply of CO2 nanobubbles, which offers a scalable avenue for developing advanced materials for various applications, including sensors for heavy metal ion detection in wastewater. The conventional synthesis method that relied on sodium dodecyl sulphate (SDS) surfactants without CO2 nanobubbles yielded CQDs with a significantly lower quantum yield of 11.2%. In short, incorporating CO2 nanobubbles with electrochemical techniques enhanced quantum yield and superior control over the size and shape of the synthesized CQDs. This novel method successfully produced CQDs with scalable distinct morphologies and provided a new understanding of the CQD synthesis mechanism, with potential applications in portable sensing for environmental monitoring and water quality management.
AB - Carbon quantum dots (CQDs) offer significant promise across industries due to their distinctive optical properties and strong biocompatibility. However, conventional synthesis methods frequently need more precision in controlling nanoparticle size, shape, and uniformity, limiting their versatility in diverse applications. Therefore, this study introduced an innovative approach to synthesising CQDs by combining electrochemical techniques with carbon dioxide (CO2) nanobubbles, circumventing the need for conventional surfactant-based exfoliation. According to the findings, the synthesised CQDs exhibited remarkable properties, including a high quantum yield of 26.17% and an average particle size of 2.24 ± 1.07 nm. Such characteristics render them exceptionally suitable for portable sensors for heavy metal detection in wastewater. Moreover, the investigation revealed the outstanding selectivity of the synthesised CQDs, particularly towards iron (Fe3+) ions, but demonstrated limited reactivity towards lead (Pb2+) and copper (Cu2+) ions. The novel approach also generated non-toxic CQD under the supply of CO2 nanobubbles, which offers a scalable avenue for developing advanced materials for various applications, including sensors for heavy metal ion detection in wastewater. The conventional synthesis method that relied on sodium dodecyl sulphate (SDS) surfactants without CO2 nanobubbles yielded CQDs with a significantly lower quantum yield of 11.2%. In short, incorporating CO2 nanobubbles with electrochemical techniques enhanced quantum yield and superior control over the size and shape of the synthesized CQDs. This novel method successfully produced CQDs with scalable distinct morphologies and provided a new understanding of the CQD synthesis mechanism, with potential applications in portable sensing for environmental monitoring and water quality management.
KW - Carbon dioxide nanobubbles exfoliation
KW - Carbon quantum dots
KW - Fe detection
KW - Fluorescence quenching
UR - http://www.scopus.com/inward/record.url?scp=85189755565&partnerID=8YFLogxK
U2 - 10.1016/j.jece.2024.112715
DO - 10.1016/j.jece.2024.112715
M3 - Article
AN - SCOPUS:85189755565
SN - 2213-3437
VL - 12
JO - Journal of Environmental Chemical Engineering
JF - Journal of Environmental Chemical Engineering
IS - 3
M1 - 112715
ER -