Synthesis, characterization and catalytic properties of SeMCM-41 molecular sieves: Oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone

N. Narender; K. Suresh Kumar Reddy; K. V.V. Krishna Mohan; S. J. Kulkarni; Angela Koeckritrz; K. V. Raghavan

doi:10.1007/s10934-010-9383-3

Synthesis, characterization and catalytic properties of SeMCM-41 molecular sieves: Oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone

N. Narender
, K. Suresh Kumar Reddy
, K. V.V. Krishna Mohan
, S. J. Kulkarni
, Angela Koeckritrz
, K. V. Raghavan

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Selenium substituted MCM-41(SeMCM-41) samples have been synthesized by using hydrothermal method and characterized by spectroscopic techniques. The oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone with hydrogen peroxide in the presence of SeMCM-41 as catalyst in acetic acid is described. The catalyst exhibits excellent substrate conversion and product selectivity. It was found to be a true heterogeneous catalyst as the activity was practically unaffected upon recycling. The highest conversion at highest selectivity has been obtained at 100 C. Different parameters effecting the oxidation of 2-methylnaphthalene with hydrogen peroxide on SeMCM-41 are described.

Original language	British English
Pages (from-to)	337-343
Number of pages	7
Journal	Journal of Porous Materials
Volume	18
Issue number	3
DOIs	https://doi.org/10.1007/s10934-010-9383-3
State	Published - Jun 2011

Keywords

2-methylnaphthalene
Hydrogen peroxide
Oxidation
SeMCM-41

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10.1007/s10934-010-9383-3

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@article{aa104624d1a942b1ad80061eb9e11b43,

title = "Synthesis, characterization and catalytic properties of SeMCM-41 molecular sieves: Oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone",

abstract = "Selenium substituted MCM-41(SeMCM-41) samples have been synthesized by using hydrothermal method and characterized by spectroscopic techniques. The oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone with hydrogen peroxide in the presence of SeMCM-41 as catalyst in acetic acid is described. The catalyst exhibits excellent substrate conversion and product selectivity. It was found to be a true heterogeneous catalyst as the activity was practically unaffected upon recycling. The highest conversion at highest selectivity has been obtained at 100 C. Different parameters effecting the oxidation of 2-methylnaphthalene with hydrogen peroxide on SeMCM-41 are described.",

keywords = "2-methylnaphthalene, Hydrogen peroxide, Oxidation, SeMCM-41",

author = "N. Narender and Reddy, \{K. Suresh Kumar\} and \{Krishna Mohan\}, \{K. V.V.\} and Kulkarni, \{S. J.\} and Angela Koeckritrz and Raghavan, \{K. V.\}",

note = "Funding Information: Acknowledgments K.S.K.R is thankful to CSIR, New Delhi for the award of SRF-GATE fellowship.",

year = "2011",

month = jun,

doi = "10.1007/s10934-010-9383-3",

language = "British English",

volume = "18",

pages = "337--343",

journal = "Journal of Porous Materials",

issn = "1380-2224",

publisher = "Springer Netherlands",

number = "3",

}

TY - JOUR

T1 - Synthesis, characterization and catalytic properties of SeMCM-41 molecular sieves

T2 - Oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone

AU - Narender, N.

AU - Reddy, K. Suresh Kumar

AU - Krishna Mohan, K. V.V.

AU - Kulkarni, S. J.

AU - Koeckritrz, Angela

AU - Raghavan, K. V.

N1 - Funding Information: Acknowledgments K.S.K.R is thankful to CSIR, New Delhi for the award of SRF-GATE fellowship.

PY - 2011/6

Y1 - 2011/6

N2 - Selenium substituted MCM-41(SeMCM-41) samples have been synthesized by using hydrothermal method and characterized by spectroscopic techniques. The oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone with hydrogen peroxide in the presence of SeMCM-41 as catalyst in acetic acid is described. The catalyst exhibits excellent substrate conversion and product selectivity. It was found to be a true heterogeneous catalyst as the activity was practically unaffected upon recycling. The highest conversion at highest selectivity has been obtained at 100 C. Different parameters effecting the oxidation of 2-methylnaphthalene with hydrogen peroxide on SeMCM-41 are described.

AB - Selenium substituted MCM-41(SeMCM-41) samples have been synthesized by using hydrothermal method and characterized by spectroscopic techniques. The oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone with hydrogen peroxide in the presence of SeMCM-41 as catalyst in acetic acid is described. The catalyst exhibits excellent substrate conversion and product selectivity. It was found to be a true heterogeneous catalyst as the activity was practically unaffected upon recycling. The highest conversion at highest selectivity has been obtained at 100 C. Different parameters effecting the oxidation of 2-methylnaphthalene with hydrogen peroxide on SeMCM-41 are described.

KW - 2-methylnaphthalene

KW - Hydrogen peroxide

KW - Oxidation

KW - SeMCM-41

UR - https://www.scopus.com/pages/publications/84867399626

U2 - 10.1007/s10934-010-9383-3

DO - 10.1007/s10934-010-9383-3

M3 - Article

AN - SCOPUS:84867399626

SN - 1380-2224

VL - 18

SP - 337

EP - 343

JO - Journal of Porous Materials

JF - Journal of Porous Materials

IS - 3

ER -

Synthesis, characterization and catalytic properties of SeMCM-41 molecular sieves: Oxidation of 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone

Abstract

Keywords

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