Synthesis and size control of luminescent ZnSe nanocrystals by a microemulsion-gas contacting technique

Georgios N. Karanikolos; Paschalis Alexandridis; Grigorios Itskos; Athos Petrou; T. J. Mountziaris

doi:10.1021/la035397+

Synthesis and size control of luminescent ZnSe nanocrystals by a microemulsion-gas contacting technique

Georgios N. Karanikolos
, Paschalis Alexandridis
, Grigorios Itskos
, Athos Petrou
, T. J. Mountziaris

Chemical and Petroleum Engineering

Research output: Contribution to journal › Letter › peer-review

91 Scopus citations

Abstract

A scalable method for controlled synthesis of luminescent compound semiconductor nanocrystals (quantum dots) using microemulsion-gas contacting at room temperature is reported. The technique exploits the dispersed phase of a microemulsion to form numerous identical nanoreactors. ZnSe quantum dots were synthesized by reacting hydrogen selenide gas with diethylzinc dissolved in the heptane nanodroplets of a microemulsion formed by self-assembly of a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) amphiphilic block copolymer in formamide. A single nanocrystal is grown in each nanodroplet, thus allowing good control of particle size by manipulation of the initial diethylzinc concentration in the heptane. The ZnSe nanocrystals exhibit size-dependent luminescence and excellent photostability.

Original language	British English
Pages (from-to)	550-553
Number of pages	4
Journal	Langmuir
Volume	20
Issue number	3
DOIs	https://doi.org/10.1021/la035397+
State	Published - 3 Feb 2004

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10.1021/la035397+

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title = "Synthesis and size control of luminescent ZnSe nanocrystals by a microemulsion-gas contacting technique",

abstract = "A scalable method for controlled synthesis of luminescent compound semiconductor nanocrystals (quantum dots) using microemulsion-gas contacting at room temperature is reported. The technique exploits the dispersed phase of a microemulsion to form numerous identical nanoreactors. ZnSe quantum dots were synthesized by reacting hydrogen selenide gas with diethylzinc dissolved in the heptane nanodroplets of a microemulsion formed by self-assembly of a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) amphiphilic block copolymer in formamide. A single nanocrystal is grown in each nanodroplet, thus allowing good control of particle size by manipulation of the initial diethylzinc concentration in the heptane. The ZnSe nanocrystals exhibit size-dependent luminescence and excellent photostability.",

author = "Karanikolos, \{Georgios N.\} and Paschalis Alexandridis and Grigorios Itskos and Athos Petrou and Mountziaris, \{T. J.\}",

note = "Funding Information: * Project supported by the National Natural Science Foundation of China and the Foundation of Xi'an Laboratory of Loess and Quaternary Geology, Chinese Academy of Sciences. * * Also at Institute of Geology, Chinese Academy of Sciences, Beijing 100029, China.",

year = "2004",

month = feb,

day = "3",

doi = "10.1021/la035397+",

language = "British English",

volume = "20",

pages = "550--553",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "3",

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TY - JOUR

T1 - Synthesis and size control of luminescent ZnSe nanocrystals by a microemulsion-gas contacting technique

AU - Karanikolos, Georgios N.

AU - Alexandridis, Paschalis

AU - Itskos, Grigorios

AU - Petrou, Athos

AU - Mountziaris, T. J.

N1 - Funding Information: * Project supported by the National Natural Science Foundation of China and the Foundation of Xi'an Laboratory of Loess and Quaternary Geology, Chinese Academy of Sciences. * * Also at Institute of Geology, Chinese Academy of Sciences, Beijing 100029, China.

PY - 2004/2/3

Y1 - 2004/2/3

N2 - A scalable method for controlled synthesis of luminescent compound semiconductor nanocrystals (quantum dots) using microemulsion-gas contacting at room temperature is reported. The technique exploits the dispersed phase of a microemulsion to form numerous identical nanoreactors. ZnSe quantum dots were synthesized by reacting hydrogen selenide gas with diethylzinc dissolved in the heptane nanodroplets of a microemulsion formed by self-assembly of a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) amphiphilic block copolymer in formamide. A single nanocrystal is grown in each nanodroplet, thus allowing good control of particle size by manipulation of the initial diethylzinc concentration in the heptane. The ZnSe nanocrystals exhibit size-dependent luminescence and excellent photostability.

AB - A scalable method for controlled synthesis of luminescent compound semiconductor nanocrystals (quantum dots) using microemulsion-gas contacting at room temperature is reported. The technique exploits the dispersed phase of a microemulsion to form numerous identical nanoreactors. ZnSe quantum dots were synthesized by reacting hydrogen selenide gas with diethylzinc dissolved in the heptane nanodroplets of a microemulsion formed by self-assembly of a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) amphiphilic block copolymer in formamide. A single nanocrystal is grown in each nanodroplet, thus allowing good control of particle size by manipulation of the initial diethylzinc concentration in the heptane. The ZnSe nanocrystals exhibit size-dependent luminescence and excellent photostability.

UR - https://www.scopus.com/pages/publications/1242265528

U2 - 10.1021/la035397+

DO - 10.1021/la035397+

M3 - Letter

AN - SCOPUS:1242265528

SN - 0743-7463

VL - 20

SP - 550

EP - 553

JO - Langmuir

JF - Langmuir

IS - 3

ER -

Synthesis and size control of luminescent ZnSe nanocrystals by a microemulsion-gas contacting technique

Abstract

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