Synthesis and characterization of a CaFe2O4 catalyst for oleic acid esterification

Huei Ruey Ong, Md Maksudur Rahman Khan, Abu Yousuf, Nor Amalina Hussain, Chin Kui Cheng

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

Esterification of free fatty acid (oleic acid) with ethanol over a calcium ferrite catalyst was investigated in the present study. The calcium ferrite catalyst (CaFe2O4) was synthesized by the sol-gel method, which exhibited high catalytic activity for esterification of oleic acid. The morphology and size (500-1000 nm) of the synthesized catalyst were observed by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) was used to ensure the absence of impurities. The orthorhombic structure of calcium ferrite was exposed by X-ray diffractometry (XRD). The effects of reaction variables such as catalyst loading, methanol to acid ratio, reaction time and temperature on the conversion of fatty acids were studied. The optimum conditions for the esterification process was a molar ratio of alcohol to oleic acid at 12:1 with 5 wt% of CaFe2O4 at 70 °C with a reaction time of 2 h. XRD patterns of the recycled catalyst evidenced that the catalyst structure was unchanged up to the 3rd cycle, which indicated the long life of the catalyst.

Original languageBritish English
Pages (from-to)100362-100368
Number of pages7
JournalRSC Advances
Volume5
Issue number121
DOIs
StatePublished - 2015

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