Surface modification of TiO2 nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems

T. O. Siyanbola; A. A. Ajayi; S. Vinukonda; K. K. Jena; S. M. Alhassan; P. Basak; E. T. Akintayo; Ramanuj Narayan; K. V.S.N. Raju

doi:10.1016/j.porgcoat.2021.106469

Surface modification of TiO₂ nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems

T. O. Siyanbola, A. A. Ajayi, S. Vinukonda, K. K. Jena, S. M. Alhassan, P. Basak, E. T. Akintayo, Ramanuj Narayan, K. V.S.N. Raju

Chemical and Petroleum Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Surface modification of peripheral hydroxyl groups of TiO₂ with trimethylolpropane (TMP) was successfully carried out and characterized. This hybrid material (TiO₂-TMP) was added in percentages to a polyol blend of castor seed oil (a renewable resource and nontoxic material) and poly(epichlorohydrin)-triol (PECH-triol) {a cross-linker}. After ultrasonication of the polyol blend with TiO₂-TMP, through a one-pot synthesis, the mixture was made to react with polymeric 4,4′-methylene diphenyl diisocyanate (PMDI) using 4-Methyl-2-pentanone as a reacting solvent. The synthesized PECH-triol and composite coating films structural elucidation was carried out using FTIR, ¹H NMR and ¹³C NMR. The pristine/undoped and composite films were subjected to specific coating evaluations such as morphology (FESEM), XRD, thermal stability, mechanical property (UTM), chemical resistance, antimicrobial activity and corrosion resistance (Tafel plot). The doped composites showed improved coating properties, especially PU-TiO₂-TMP (1.0 wt%), which possesses the highest percentage of TiO₂-TMP nanoparticle.

Original language	British English
Article number	106469
Journal	Progress in Organic Coatings
Volume	161
DOIs	https://doi.org/10.1016/j.porgcoat.2021.106469
State	Published - Dec 2021

Keywords

Antimicrobial
Corrosion resistance
Nanoparticle
Poly(epichlorohydrin)-triol
Renewable

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10.1016/j.porgcoat.2021.106469

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Siyanbola, T. O., Ajayi, A. A., Vinukonda, S., Jena, K. K., Alhassan, S. M., Basak, P., Akintayo, E. T., Narayan, R., & Raju, K. V. S. N. (2021). Surface modification of TiO₂ nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems. Progress in Organic Coatings, 161, Article 106469. https://doi.org/10.1016/j.porgcoat.2021.106469

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title = "Surface modification of TiO2 nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems",

abstract = "Surface modification of peripheral hydroxyl groups of TiO2 with trimethylolpropane (TMP) was successfully carried out and characterized. This hybrid material (TiO2-TMP) was added in percentages to a polyol blend of castor seed oil (a renewable resource and nontoxic material) and poly(epichlorohydrin)-triol (PECH-triol) \{a cross-linker\}. After ultrasonication of the polyol blend with TiO2-TMP, through a one-pot synthesis, the mixture was made to react with polymeric 4,4′-methylene diphenyl diisocyanate (PMDI) using 4-Methyl-2-pentanone as a reacting solvent. The synthesized PECH-triol and composite coating films structural elucidation was carried out using FTIR, 1H NMR and 13C NMR. The pristine/undoped and composite films were subjected to specific coating evaluations such as morphology (FESEM), XRD, thermal stability, mechanical property (UTM), chemical resistance, antimicrobial activity and corrosion resistance (Tafel plot). The doped composites showed improved coating properties, especially PU-TiO2-TMP (1.0 wt\%), which possesses the highest percentage of TiO2-TMP nanoparticle.",

keywords = "Antimicrobial, Corrosion resistance, Nanoparticle, Poly(epichlorohydrin)-triol, Renewable",

author = "Siyanbola, \{T. O.\} and Ajayi, \{A. A.\} and S. Vinukonda and Jena, \{K. K.\} and Alhassan, \{S. M.\} and P. Basak and Akintayo, \{E. T.\} and Ramanuj Narayan and Raju, \{K. V.S.N.\}",

note = "Funding Information: The Council for Scientific and Industrial Research (CSIR) and The World Academy of Science (TWAS) (Italy) is well appreciated by the author (Dr Tolutope Oluwasegun Siyanbola) for the 2016 Postdoctoral Fellowship Award (FR number: 3240293580). Appreciation also goes to the Indian Institute of Chemical Technology (IICT), Hyderabad, India and Covenant University, Ota, Nigeria, for respectively providing the platform for my research/bench work and grant leave. Thanks to Ramu Enishetty of Polymers and Functional Materials Division IICT for his laboratory contributions. Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2021",

month = dec,

doi = "10.1016/j.porgcoat.2021.106469",

language = "British English",

volume = "161",

journal = "Progress in Organic Coatings",

issn = "0300-9440",

publisher = "Elsevier B.V.",

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Siyanbola, TO, Ajayi, AA, Vinukonda, S, Jena, KK, Alhassan, SM, Basak, P, Akintayo, ET, Narayan, R & Raju, KVSN 2021, 'Surface modification of TiO₂ nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems', Progress in Organic Coatings, vol. 161, 106469. https://doi.org/10.1016/j.porgcoat.2021.106469

TY - JOUR

T1 - Surface modification of TiO2 nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems

AU - Siyanbola, T. O.

AU - Ajayi, A. A.

AU - Vinukonda, S.

AU - Jena, K. K.

AU - Alhassan, S. M.

AU - Basak, P.

AU - Akintayo, E. T.

AU - Narayan, Ramanuj

AU - Raju, K. V.S.N.

N1 - Funding Information: The Council for Scientific and Industrial Research (CSIR) and The World Academy of Science (TWAS) (Italy) is well appreciated by the author (Dr Tolutope Oluwasegun Siyanbola) for the 2016 Postdoctoral Fellowship Award (FR number: 3240293580). Appreciation also goes to the Indian Institute of Chemical Technology (IICT), Hyderabad, India and Covenant University, Ota, Nigeria, for respectively providing the platform for my research/bench work and grant leave. Thanks to Ramu Enishetty of Polymers and Functional Materials Division IICT for his laboratory contributions. Publisher Copyright: © 2021 Elsevier B.V.

PY - 2021/12

Y1 - 2021/12

N2 - Surface modification of peripheral hydroxyl groups of TiO2 with trimethylolpropane (TMP) was successfully carried out and characterized. This hybrid material (TiO2-TMP) was added in percentages to a polyol blend of castor seed oil (a renewable resource and nontoxic material) and poly(epichlorohydrin)-triol (PECH-triol) {a cross-linker}. After ultrasonication of the polyol blend with TiO2-TMP, through a one-pot synthesis, the mixture was made to react with polymeric 4,4′-methylene diphenyl diisocyanate (PMDI) using 4-Methyl-2-pentanone as a reacting solvent. The synthesized PECH-triol and composite coating films structural elucidation was carried out using FTIR, 1H NMR and 13C NMR. The pristine/undoped and composite films were subjected to specific coating evaluations such as morphology (FESEM), XRD, thermal stability, mechanical property (UTM), chemical resistance, antimicrobial activity and corrosion resistance (Tafel plot). The doped composites showed improved coating properties, especially PU-TiO2-TMP (1.0 wt%), which possesses the highest percentage of TiO2-TMP nanoparticle.

AB - Surface modification of peripheral hydroxyl groups of TiO2 with trimethylolpropane (TMP) was successfully carried out and characterized. This hybrid material (TiO2-TMP) was added in percentages to a polyol blend of castor seed oil (a renewable resource and nontoxic material) and poly(epichlorohydrin)-triol (PECH-triol) {a cross-linker}. After ultrasonication of the polyol blend with TiO2-TMP, through a one-pot synthesis, the mixture was made to react with polymeric 4,4′-methylene diphenyl diisocyanate (PMDI) using 4-Methyl-2-pentanone as a reacting solvent. The synthesized PECH-triol and composite coating films structural elucidation was carried out using FTIR, 1H NMR and 13C NMR. The pristine/undoped and composite films were subjected to specific coating evaluations such as morphology (FESEM), XRD, thermal stability, mechanical property (UTM), chemical resistance, antimicrobial activity and corrosion resistance (Tafel plot). The doped composites showed improved coating properties, especially PU-TiO2-TMP (1.0 wt%), which possesses the highest percentage of TiO2-TMP nanoparticle.

KW - Antimicrobial

KW - Corrosion resistance

KW - Nanoparticle

KW - Poly(epichlorohydrin)-triol

KW - Renewable

UR - https://www.scopus.com/pages/publications/85112745039

U2 - 10.1016/j.porgcoat.2021.106469

DO - 10.1016/j.porgcoat.2021.106469

M3 - Article

AN - SCOPUS:85112745039

SN - 0300-9440

VL - 161

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

M1 - 106469

ER -

Surface modification of TiO₂ nanoparticles with 1,1,1-Tris(hydroxymethyl)propane and its coating application effects on castor seed oil-PECH blend based urethane systems

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Keywords

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