Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection: Journal of Physical Chemistry Letters

A.T. Gidey; Y. Haruta; A.P. Herman; M. Grodzicki; A.M. Melnychenko; D. Majchrzak; S. Mahato; E. Rogowicz; M. Syperek; R. Kudrawiec; M.I. Saidaminov; A.L. Abdelhady

doi:10.1021/acs.jpclett.3c02061

Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection: Journal of Physical Chemistry Letters

A.T. Gidey, Y. Haruta, A.P. Herman, M. Grodzicki, A.M. Melnychenko, D. Majchrzak, S. Mahato, E. Rogowicz, M. Syperek, R. Kudrawiec, M.I. Saidaminov, A.L. Abdelhady

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The surface quality of lead halide perovskite crystals can extremely influence their optoelectronic properties and device performance. Here, we report a surface engineering crystallization technique in which we in situ grow a polycrystalline methylammonium lead tribromide (MAPbBr3) film on top of bulk mm-sized single crystals. Such MAPbBr3 crystals with a MAPbBr3 passivating film display intense green emission under UV light. X-ray photoelectron spectroscopy demonstrates that these crystals with emissive surfaces are compositionally different from typical MAPbBr3 crystals that show no emission under UV light. Time-resolved photoluminescence and electrical measurements indicate that the MAPbBr3 film/MAPbBr3 crystals possess less surface defects compared to the bare MAPbBr3 crystals. Therefore, X-ray detectors fabricated using the surface-engineered MAPbBr3 crystals provide an almost 5 times improved sensitivity to X-rays and a more stable baseline drift with respect to the typical MAPbBr3 crystals. © 2023 The Authors. Published by American Chemical Society.

Original language	British English
Pages (from-to)	9136-9144
Number of pages	9
Journal	J. Phys. Chem. Lett.
Volume	14
Issue number	40
DOIs	https://doi.org/10.1021/acs.jpclett.3c02061
State	Published - 2023

Keywords

Chemical detection
Lead compounds
Passivation
Perovskite
Single crystals
Surface defects
X ray detectors
American Chemical Society
Device performance
Halide perovskites
Optoelectronics devices
Optoelectronics property
Perovskite crystal
Polycrystalline
Surface engineering
UV-light
X-ray detections
X ray photoelectron spectroscopy

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10.1021/acs.jpclett.3c02061

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85174751806&doi=10.1021%2facs.jpclett.3c02061&partnerID=40&md5=d9029bc4b325826e99afa9edd42b495f

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Gidey, A. T., Haruta, Y., Herman, A. P., Grodzicki, M., Melnychenko, A. M., Majchrzak, D., Mahato, S., Rogowicz, E., Syperek, M., Kudrawiec, R., Saidaminov, M. I., & Abdelhady, A. L. (2023). Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection: Journal of Physical Chemistry Letters. J. Phys. Chem. Lett., 14(40), 9136-9144. https://doi.org/10.1021/acs.jpclett.3c02061

@article{fcafeb5fd1e3411dad96e8bbfec6b96d,

title = "Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection: Journal of Physical Chemistry Letters",

abstract = "The surface quality of lead halide perovskite crystals can extremely influence their optoelectronic properties and device performance. Here, we report a surface engineering crystallization technique in which we in situ grow a polycrystalline methylammonium lead tribromide (MAPbBr3) film on top of bulk mm-sized single crystals. Such MAPbBr3 crystals with a MAPbBr3 passivating film display intense green emission under UV light. X-ray photoelectron spectroscopy demonstrates that these crystals with emissive surfaces are compositionally different from typical MAPbBr3 crystals that show no emission under UV light. Time-resolved photoluminescence and electrical measurements indicate that the MAPbBr3 film/MAPbBr3 crystals possess less surface defects compared to the bare MAPbBr3 crystals. Therefore, X-ray detectors fabricated using the surface-engineered MAPbBr3 crystals provide an almost 5 times improved sensitivity to X-rays and a more stable baseline drift with respect to the typical MAPbBr3 crystals. {\textcopyright} 2023 The Authors. Published by American Chemical Society.",

keywords = "Chemical detection, Lead compounds, Passivation, Perovskite, Single crystals, Surface defects, X ray detectors, American Chemical Society, Device performance, Halide perovskites, Optoelectronics devices, Optoelectronics property, Perovskite crystal, Polycrystalline, Surface engineering, UV-light, X-ray detections, X ray photoelectron spectroscopy",

author = "A.T. Gidey and Y. Haruta and A.P. Herman and M. Grodzicki and A.M. Melnychenko and D. Majchrzak and S. Mahato and E. Rogowicz and M. Syperek and R. Kudrawiec and M.I. Saidaminov and A.L. Abdelhady",

note = "Export Date: 11 January 2024; Cited By: 1; Correspondence Address: R. Kudrawiec; {\L}UKASIEWICZ Research Network PORT-Polish Center for Technology Development, Wroc{\l}aw, 54-066, Poland; email: [email protected]; M.I. Saidaminov; Department of Chemistry, University of Victoria, Victoria, 3800 Finnerty Road, V8P 5C2, Canada; email: [email protected]; A.L. Abdelhady; Department of Chemistry, Khalifa University, Abu Dhabi, United Arab Emirates; email: [email protected]",

year = "2023",

doi = "10.1021/acs.jpclett.3c02061",

language = "British English",

volume = "14",

pages = "9136--9144",

journal = "J. Phys. Chem. Lett.",

issn = "1948-7185",

publisher = "American Chemical Society",

number = "40",

}

Gidey, AT, Haruta, Y, Herman, AP, Grodzicki, M, Melnychenko, AM, Majchrzak, D, Mahato, S, Rogowicz, E, Syperek, M, Kudrawiec, R, Saidaminov, MI & Abdelhady, AL 2023, 'Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection: Journal of Physical Chemistry Letters', J. Phys. Chem. Lett., vol. 14, no. 40, pp. 9136-9144. https://doi.org/10.1021/acs.jpclett.3c02061

TY - JOUR

T1 - Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection

T2 - Journal of Physical Chemistry Letters

AU - Gidey, A.T.

AU - Haruta, Y.

AU - Herman, A.P.

AU - Grodzicki, M.

AU - Melnychenko, A.M.

AU - Majchrzak, D.

AU - Mahato, S.

AU - Rogowicz, E.

AU - Syperek, M.

AU - Kudrawiec, R.

AU - Saidaminov, M.I.

AU - Abdelhady, A.L.

N1 - Export Date: 11 January 2024; Cited By: 1; Correspondence Address: R. Kudrawiec; ŁUKASIEWICZ Research Network PORT-Polish Center for Technology Development, Wrocław, 54-066, Poland; email: [email protected]; M.I. Saidaminov; Department of Chemistry, University of Victoria, Victoria, 3800 Finnerty Road, V8P 5C2, Canada; email: [email protected]; A.L. Abdelhady; Department of Chemistry, Khalifa University, Abu Dhabi, United Arab Emirates; email: [email protected]

PY - 2023

Y1 - 2023

N2 - The surface quality of lead halide perovskite crystals can extremely influence their optoelectronic properties and device performance. Here, we report a surface engineering crystallization technique in which we in situ grow a polycrystalline methylammonium lead tribromide (MAPbBr3) film on top of bulk mm-sized single crystals. Such MAPbBr3 crystals with a MAPbBr3 passivating film display intense green emission under UV light. X-ray photoelectron spectroscopy demonstrates that these crystals with emissive surfaces are compositionally different from typical MAPbBr3 crystals that show no emission under UV light. Time-resolved photoluminescence and electrical measurements indicate that the MAPbBr3 film/MAPbBr3 crystals possess less surface defects compared to the bare MAPbBr3 crystals. Therefore, X-ray detectors fabricated using the surface-engineered MAPbBr3 crystals provide an almost 5 times improved sensitivity to X-rays and a more stable baseline drift with respect to the typical MAPbBr3 crystals. © 2023 The Authors. Published by American Chemical Society.

AB - The surface quality of lead halide perovskite crystals can extremely influence their optoelectronic properties and device performance. Here, we report a surface engineering crystallization technique in which we in situ grow a polycrystalline methylammonium lead tribromide (MAPbBr3) film on top of bulk mm-sized single crystals. Such MAPbBr3 crystals with a MAPbBr3 passivating film display intense green emission under UV light. X-ray photoelectron spectroscopy demonstrates that these crystals with emissive surfaces are compositionally different from typical MAPbBr3 crystals that show no emission under UV light. Time-resolved photoluminescence and electrical measurements indicate that the MAPbBr3 film/MAPbBr3 crystals possess less surface defects compared to the bare MAPbBr3 crystals. Therefore, X-ray detectors fabricated using the surface-engineered MAPbBr3 crystals provide an almost 5 times improved sensitivity to X-rays and a more stable baseline drift with respect to the typical MAPbBr3 crystals. © 2023 The Authors. Published by American Chemical Society.

KW - Chemical detection

KW - Lead compounds

KW - Passivation

KW - Perovskite

KW - Single crystals

KW - Surface defects

KW - X ray detectors

KW - American Chemical Society

KW - Device performance

KW - Halide perovskites

KW - Optoelectronics devices

KW - Optoelectronics property

KW - Perovskite crystal

KW - Polycrystalline

KW - Surface engineering

KW - UV-light

KW - X-ray detections

KW - X ray photoelectron spectroscopy

U2 - 10.1021/acs.jpclett.3c02061

DO - 10.1021/acs.jpclett.3c02061

M3 - Article

SN - 1948-7185

VL - 14

SP - 9136

EP - 9144

JO - J. Phys. Chem. Lett.

JF - J. Phys. Chem. Lett.

IS - 40

ER -

Surface Engineering of Methylammonium Lead Bromide Perovskite Crystals for Enhanced X-ray Detection: Journal of Physical Chemistry Letters

Abstract

Keywords

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