TY - JOUR
T1 - Sonoelectrochemistry
T2 - Ultrasound-assisted Organic Electrosynthesis
AU - de Bitencourt Rodrigues, Higor
AU - Oliveira de Brito Lira, Jéssica
AU - Padoin, Natan
AU - Soares, Cíntia
AU - Qurashi, Ahsanulhaq
AU - Ahmed, Nisar
N1 - Funding Information:
Support from Cardiff University to Dr. Nisar Ahmed (EPSRC Investigator, School of Chemistry) is gratefully acknowledged. This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior – Brasil (CAPES) – Finance Code 001. The authors are also thankful to the Conselho Nacional de Desenvolvimento Científico e Tecnológico – Brasil (CNPq). We would like to thank Dr. Muhammad Imran (King Khalid University) for valuable technical assistance and discussions.
Publisher Copyright:
© 2021 American Chemical Society
PY - 2021/7/26
Y1 - 2021/7/26
N2 - The application of ultrasound with electrochemistry in organic chemistry (known as organic sonoelectrochemistry) accelerates the activation process of chemical reactions. This hybrid technology enhances electrical efficiency and modifies and increases the product yield. Moreover, it facilitates the mass transfer phenomena and the processes of cleaning, degassing, and activation of the electrode surfaces; maintains higher current densities for efficient chemical transformations; and also works efficiently for mixing of reactants in multiphase systems. The ultrasound technology has a prominent effect in heterogeneous reaction systems especially during the solid (electrode)-liquid (electrolytic mixture) interfacial cavitation process. The ultrasound technology gains attention due to its fundamental and positive effect in organic chemistry to make possible the challenging electrosynthetic processes. Herein, we report the sonoelectrosynthetic methods that will help researchers to understand and apply this methodology for scale-up of processes in organic synthesis and also in more modern innovative continuous-flow organic electrochemistry. Therefore, this study will provide valuable insight into the effects caused by ultrasound-assisted electrosynthesis and how this technology revolutionizes organic synthesis. It is believed that the hybrid sonoelectrochemical synthesis serves as a solution to the limitations of the commercialization of synthetic processes and offers a new, modern aspect in organic synthesis in a clean, hassle-free, and sustainable approach.
AB - The application of ultrasound with electrochemistry in organic chemistry (known as organic sonoelectrochemistry) accelerates the activation process of chemical reactions. This hybrid technology enhances electrical efficiency and modifies and increases the product yield. Moreover, it facilitates the mass transfer phenomena and the processes of cleaning, degassing, and activation of the electrode surfaces; maintains higher current densities for efficient chemical transformations; and also works efficiently for mixing of reactants in multiphase systems. The ultrasound technology has a prominent effect in heterogeneous reaction systems especially during the solid (electrode)-liquid (electrolytic mixture) interfacial cavitation process. The ultrasound technology gains attention due to its fundamental and positive effect in organic chemistry to make possible the challenging electrosynthetic processes. Herein, we report the sonoelectrosynthetic methods that will help researchers to understand and apply this methodology for scale-up of processes in organic synthesis and also in more modern innovative continuous-flow organic electrochemistry. Therefore, this study will provide valuable insight into the effects caused by ultrasound-assisted electrosynthesis and how this technology revolutionizes organic synthesis. It is believed that the hybrid sonoelectrochemical synthesis serves as a solution to the limitations of the commercialization of synthetic processes and offers a new, modern aspect in organic synthesis in a clean, hassle-free, and sustainable approach.
KW - Heterogeneous catalysis
KW - Organic sonoelectrosynthesis
KW - Sustainable chemistry
KW - Synthetic sonoelectrochemistry and organic reaction engineering
KW - Ultrasound
UR - http://www.scopus.com/inward/record.url?scp=85111266097&partnerID=8YFLogxK
U2 - 10.1021/acssuschemeng.1c02989
DO - 10.1021/acssuschemeng.1c02989
M3 - Review article
AN - SCOPUS:85111266097
SN - 2168-0485
VL - 9
SP - 9590
EP - 9603
JO - ACS Sustainable Chemistry and Engineering
JF - ACS Sustainable Chemistry and Engineering
IS - 29
ER -