Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides

V. R. Choudhary; D. K. Dumbre; B. S. Uphade; V. S. Narkhede

doi:10.1016/j.molcata.2004.01.009

Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides

V. R. Choudhary
, D. K. Dumbre
, B. S. Uphade
, V. S. Narkhede

National Chemical Laboratory India

Research output: Contribution to journal › Article › peer-review

125 Scopus citations

Abstract

Performance of Mn-Al, Co-Al, Ni-Al, Zn-Al, Mg-Fe, Mn-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-Cr, Ni-Cr, Cu-Cr, and Zn-Cr layered double hydroxides (LDH) and/or mixed hydroxides (HD) solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using TBHP as an oxidizing agent in the absence of any solvent. The Mn, Cu, and Co containing LDH solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation of benzyl alcohol to benzaldehyde.

Original language	British English
Pages (from-to)	129-135
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	215
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2004.01.009
State	Published - 14 Jun 2004

Keywords

Oxidation of benzyl alcohol to benzaldehyde
Solvent-free oxidation of benzyl alcohol
Transition metal containing hydrotalcite-like catalysts

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title = "Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides",

abstract = "Performance of Mn-Al, Co-Al, Ni-Al, Zn-Al, Mg-Fe, Mn-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-Cr, Ni-Cr, Cu-Cr, and Zn-Cr layered double hydroxides (LDH) and/or mixed hydroxides (HD) solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using TBHP as an oxidizing agent in the absence of any solvent. The Mn, Cu, and Co containing LDH solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation of benzyl alcohol to benzaldehyde.",

keywords = "Oxidation of benzyl alcohol to benzaldehyde, Solvent-free oxidation of benzyl alcohol, Transition metal containing hydrotalcite-like catalysts",

author = "Choudhary, \{V. R.\} and Dumbre, \{D. K.\} and Uphade, \{B. S.\} and Narkhede, \{V. S.\}",

note = "Funding Information: D.K. Dumbre and B.S. Uphade are grateful to CSIR, New Delhi, India, for the award of Senior Research Fellowship and Senior Research Associateship, respectively.",

year = "2004",

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doi = "10.1016/j.molcata.2004.01.009",

language = "British English",

volume = "215",

pages = "129--135",

journal = "Journal of Molecular Catalysis A: Chemical",

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Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides. / Choudhary, V. R.; Dumbre, D. K.; Uphade, B. S. et al.
In: Journal of Molecular Catalysis A: Chemical, Vol. 215, No. 1-2, 14.06.2004, p. 129-135.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides

AU - Choudhary, V. R.

AU - Dumbre, D. K.

AU - Uphade, B. S.

AU - Narkhede, V. S.

N1 - Funding Information: D.K. Dumbre and B.S. Uphade are grateful to CSIR, New Delhi, India, for the award of Senior Research Fellowship and Senior Research Associateship, respectively.

PY - 2004/6/14

Y1 - 2004/6/14

N2 - Performance of Mn-Al, Co-Al, Ni-Al, Zn-Al, Mg-Fe, Mn-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-Cr, Ni-Cr, Cu-Cr, and Zn-Cr layered double hydroxides (LDH) and/or mixed hydroxides (HD) solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using TBHP as an oxidizing agent in the absence of any solvent. The Mn, Cu, and Co containing LDH solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation of benzyl alcohol to benzaldehyde.

AB - Performance of Mn-Al, Co-Al, Ni-Al, Zn-Al, Mg-Fe, Mn-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-Cr, Ni-Cr, Cu-Cr, and Zn-Cr layered double hydroxides (LDH) and/or mixed hydroxides (HD) solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using TBHP as an oxidizing agent in the absence of any solvent. The Mn, Cu, and Co containing LDH solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation of benzyl alcohol to benzaldehyde.

KW - Oxidation of benzyl alcohol to benzaldehyde

KW - Solvent-free oxidation of benzyl alcohol

KW - Transition metal containing hydrotalcite-like catalysts

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U2 - 10.1016/j.molcata.2004.01.009

DO - 10.1016/j.molcata.2004.01.009

M3 - Article

AN - SCOPUS:1942436176

SN - 1381-1169

VL - 215

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EP - 135

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides

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Keywords

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