Selective hydrogenation of d-glucose to d-sorbitol over HY zeolite supported ruthenium nanoparticles catalysts

Dinesh Kumar Mishra; Aasif Asharaf Dabbawala; Jung Je Park; Sung Hwa Jhung; Jin Soo Hwang

doi:10.1016/j.cattod.2013.10.018

Selective hydrogenation of d-glucose to d-sorbitol over HY zeolite supported ruthenium nanoparticles catalysts

Dinesh Kumar Mishra, Aasif Asharaf Dabbawala, Jung Je Park, Sung Hwa Jhung, Jin Soo Hwang

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71 Scopus citations

Abstract

HY zeolite (HYZ) supported ruthenium (Ru) nanoparticles catalyst (Ru/HYZ) is prepared by simple impregnation method and is characterized by using energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), CO chemisorption and inductively coupled plasma (ICP) mass spectrometry. The catalyst Ru/HYZ is evaluated in hydrogenation of d-glucose and hydrogenation experiments to produce a selective product d-sorbitol were conducted batch wise in a three-phase laboratory scale reactor. The kinetics studies of d-glucose hydrogenation using the catalyst Ru/HYZ were carried out. In the operating regime studied the rate of reaction showed first orders dependency with respect to d-glucose and hydrogen. For affording maximum d-glucose conversion, yield and selectivity to d-sorbitol, the reaction conditions were also optimized.

Original language	British English
Pages (from-to)	99-107
Number of pages	9
Journal	Catalysis Today
Volume	232
DOIs	https://doi.org/10.1016/j.cattod.2013.10.018
State	Published - 1 Sep 2014

Keywords

d-Glucose
d-Sorbitol
HY zeolite
Hydrogenation
Ruthenium nanoparticles

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10.1016/j.cattod.2013.10.018

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title = "Selective hydrogenation of d-glucose to d-sorbitol over HY zeolite supported ruthenium nanoparticles catalysts",

abstract = "HY zeolite (HYZ) supported ruthenium (Ru) nanoparticles catalyst (Ru/HYZ) is prepared by simple impregnation method and is characterized by using energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), CO chemisorption and inductively coupled plasma (ICP) mass spectrometry. The catalyst Ru/HYZ is evaluated in hydrogenation of d-glucose and hydrogenation experiments to produce a selective product d-sorbitol were conducted batch wise in a three-phase laboratory scale reactor. The kinetics studies of d-glucose hydrogenation using the catalyst Ru/HYZ were carried out. In the operating regime studied the rate of reaction showed first orders dependency with respect to d-glucose and hydrogen. For affording maximum d-glucose conversion, yield and selectivity to d-sorbitol, the reaction conditions were also optimized.",

keywords = "d-Glucose, d-Sorbitol, HY zeolite, Hydrogenation, Ruthenium nanoparticles",

author = "Mishra, {Dinesh Kumar} and Dabbawala, {Aasif Asharaf} and Park, {Jung Je} and Jhung, {Sung Hwa} and Hwang, {Jin Soo}",

note = "Funding Information: This work was supported by the Institutional Research Program of KRICT (SI-1201) and by a grant ( B551179-10-03-00 ) from the cooperative R&D. Program funded by the Korea Research Council Industrial Science and Technology, Republic of Korea .",

year = "2014",

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doi = "10.1016/j.cattod.2013.10.018",

language = "British English",

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journal = "Catalysis Today",

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AU - Mishra, Dinesh Kumar

AU - Dabbawala, Aasif Asharaf

AU - Park, Jung Je

AU - Jhung, Sung Hwa

AU - Hwang, Jin Soo

N1 - Funding Information: This work was supported by the Institutional Research Program of KRICT (SI-1201) and by a grant ( B551179-10-03-00 ) from the cooperative R&D. Program funded by the Korea Research Council Industrial Science and Technology, Republic of Korea .

PY - 2014/9/1

Y1 - 2014/9/1

N2 - HY zeolite (HYZ) supported ruthenium (Ru) nanoparticles catalyst (Ru/HYZ) is prepared by simple impregnation method and is characterized by using energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), CO chemisorption and inductively coupled plasma (ICP) mass spectrometry. The catalyst Ru/HYZ is evaluated in hydrogenation of d-glucose and hydrogenation experiments to produce a selective product d-sorbitol were conducted batch wise in a three-phase laboratory scale reactor. The kinetics studies of d-glucose hydrogenation using the catalyst Ru/HYZ were carried out. In the operating regime studied the rate of reaction showed first orders dependency with respect to d-glucose and hydrogen. For affording maximum d-glucose conversion, yield and selectivity to d-sorbitol, the reaction conditions were also optimized.

AB - HY zeolite (HYZ) supported ruthenium (Ru) nanoparticles catalyst (Ru/HYZ) is prepared by simple impregnation method and is characterized by using energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), CO chemisorption and inductively coupled plasma (ICP) mass spectrometry. The catalyst Ru/HYZ is evaluated in hydrogenation of d-glucose and hydrogenation experiments to produce a selective product d-sorbitol were conducted batch wise in a three-phase laboratory scale reactor. The kinetics studies of d-glucose hydrogenation using the catalyst Ru/HYZ were carried out. In the operating regime studied the rate of reaction showed first orders dependency with respect to d-glucose and hydrogen. For affording maximum d-glucose conversion, yield and selectivity to d-sorbitol, the reaction conditions were also optimized.

KW - d-Glucose

KW - d-Sorbitol

KW - HY zeolite

KW - Hydrogenation

KW - Ruthenium nanoparticles

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DO - 10.1016/j.cattod.2013.10.018

M3 - Article

AN - SCOPUS:84901231315

SN - 0920-5861

VL - 232

SP - 99

EP - 107

JO - Catalysis Today

JF - Catalysis Today

ER -

Selective hydrogenation of d-glucose to d-sorbitol over HY zeolite supported ruthenium nanoparticles catalysts

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Keywords

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