TY - JOUR
T1 - Reviewing the mathematical validity of a fuel cell cathode model. Existence of weak bounded solution
AU - Al-arydah, Mo'tassem
AU - Carraro, Thomas
N1 - Funding Information:
TC was supported by the German Research Council (DFG) , Germany through project CA 633/2-1 . We acknowledge support by the state of Baden-Württemberg through bwHPC , Germany and the German Research Foundation (DFG) , Germany through grant INST 35/1134-1 FUGG .
Publisher Copyright:
© 2018 Elsevier Ltd
PY - 2019/3/15
Y1 - 2019/3/15
N2 - We consider a system of nonlinear PDEs in a domain with a triple phase boundary, describing electrochemical processes in a mixed conduction, solid-oxide cathode of a fuel cell. It represents oxygen diffusion (with nonlinear diffusion coefficient) in the gas phase, oxygen ion diffusion in the bulk phase, electron diffusion in the electrolyte, surface exchange (nonlinear) on the interface of gas and the (mixed conduction) electrode material and finally charge transfer (nonlinear) at the interface between the electrolyte and the electrode material. We prove the validity of the model both mathematically and numerically. In fact, we prove the existence of a bounded weak solution using the Schauder fixed point theorem. We calculate the numerical solutions for given function and parameter values, and show that they correspond to theoretical results. In particular, we provide a numerical confirmation of the a priori bounds.
AB - We consider a system of nonlinear PDEs in a domain with a triple phase boundary, describing electrochemical processes in a mixed conduction, solid-oxide cathode of a fuel cell. It represents oxygen diffusion (with nonlinear diffusion coefficient) in the gas phase, oxygen ion diffusion in the bulk phase, electron diffusion in the electrolyte, surface exchange (nonlinear) on the interface of gas and the (mixed conduction) electrode material and finally charge transfer (nonlinear) at the interface between the electrolyte and the electrode material. We prove the validity of the model both mathematically and numerically. In fact, we prove the existence of a bounded weak solution using the Schauder fixed point theorem. We calculate the numerical solutions for given function and parameter values, and show that they correspond to theoretical results. In particular, we provide a numerical confirmation of the a priori bounds.
KW - Fuel cell cathode
KW - System of PDEs
KW - Weak solution
UR - http://www.scopus.com/inward/record.url?scp=85054124733&partnerID=8YFLogxK
U2 - 10.1016/j.camwa.2018.08.001
DO - 10.1016/j.camwa.2018.08.001
M3 - Article
AN - SCOPUS:85054124733
SN - 0898-1221
VL - 77
SP - 1425
EP - 1436
JO - Computers and Mathematics with Applications
JF - Computers and Mathematics with Applications
IS - 6
ER -