Reversing the Stereoselectivity of the Intermolecular Pauson-Khand Reaction: Formation of endo-Fused Norbornadiene Adducts

Ramon Rios; Miquel A. Pericàs; Albert Moyano; Miguel A. Maestro; José Mahía

doi:10.1021/ol025649i

Reversing the Stereoselectivity of the Intermolecular Pauson-Khand Reaction: Formation of endo-Fused Norbornadiene Adducts

Ramon Rios
, Miquel A. Pericàs
, Albert Moyano
, Miguel A. Maestro
, José Mahía

Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

matrix presented An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.

Original language	British English
Pages (from-to)	1205-1208
Number of pages	4
Journal	Organic Letters
Volume	4
Issue number	7
DOIs	https://doi.org/10.1021/ol025649i
State	Published - 4 Apr 2002

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title = "Reversing the Stereoselectivity of the Intermolecular Pauson-Khand Reaction: Formation of endo-Fused Norbornadiene Adducts",

abstract = "matrix presented An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.",

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AU - Rios, Ramon

AU - Pericàs, Miquel A.

AU - Moyano, Albert

AU - Maestro, Miguel A.

AU - Mahía, José

PY - 2002/4/4

Y1 - 2002/4/4

N2 - matrix presented An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.

AB - matrix presented An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.

UR - https://www.scopus.com/pages/publications/0005993742

U2 - 10.1021/ol025649i

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JO - Organic Letters

JF - Organic Letters

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Reversing the Stereoselectivity of the Intermolecular Pauson-Khand Reaction: Formation of endo-Fused Norbornadiene Adducts

Abstract

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