Production of CO-rich hydrogen gas from methane dry reforming over Co/CeO₂ Catalyst

Production of CO-rich hydrogen gas from methane dry reforming was investigated over CeO2-supported Co catalyst. The catalyst was synthesized by wet impregnation and subsequently character-ized by field emission scanning electron microscope (FESEM), energy-dispersive X-ray spectroscopy (EDX), liquid N₂ adsorption-desorption, X-ray diffraction (XRD), Fourier transform infrared spectros-copy (FTIR) and thermogravimetric analysis (TGA) for the structure, surface and thermal properties. The catalytic activity test of the Co/CeO₂ was investigated between 923-1023 K under reaction condi-tions in a stainless steel fixed bed reactor. The composition of the products (CO and H₂) from the meth-ane dry reforming reaction was measured by gas chromatography (GC) coupled with thermal conduc-tivity detector (TCD). The effects of feed ratios and reaction temperatures were investigated on the catalytic activity toward product selectivity, yield, and syngas ratio. Significantly, the selectivity and yield of both H₂ and CO increases with feed ratio and temperature. However, the catalyst shows higher activity towards CO selectivity. The highest H₂ and CO selectivity of 19.56% and 20.95% respectively were obtained at 1023 K while the highest yield of 41.98% and 38.05% were recorded for H₂ and CO under the same condition.