TY - JOUR
T1 - Preparation of TiO2/SiO2 ceramic membranes via dip coating for the treatment of produced water
AU - Marzouk, Sara S.
AU - Naddeo, Vincenzo
AU - Banat, Fawzi
AU - Hasan, Shadi W.
N1 - Funding Information:
This publication is based upon work supported by the Khalifa University of Science and Technology under Award No. RC2-2018-009 .
Publisher Copyright:
© 2021 Elsevier Ltd
PY - 2021/6
Y1 - 2021/6
N2 - Produced water, a by-product generated from the oil and gas extraction processes, represents a major challenge in the oil and gas industry as it is generally characterized with a very high salinity and oil content. Currently used ceramic membranes for oil-water separation suffer from the low water flux in spite of their several distinctive advantages. To overcome this limitation and to increase the water flux and oil rejection, commercial ceramic TiO2 membranes were dip coated with silica (SiO2) nanoparticles at different concentrations of 0.25, 0.50, 0.75, and 1.0 wt %. Coated membranes were characterized using scanning electron microscopy (SEM), energy-dispersive x-ray sSpectroscopy (EDS), Fourier-transform infrared spectroscopy (FTIR) and Raman Spectroscopy and contact angle. Results showed that SiO2 nanoparticles were successfully deposited on the surface of the ceramic membranes confirming the dip coating approach. Furthermore, water flux of 817, 2724, 3636, 627, and 1292 L m−2 h−1 (LMH) was reported at control, 0.25, 0.50, 0.75 and 1.0 wt%; respectively. Also, contact angle reported 75°, 50°, 40°, 24°, 0° at control, 0.25, 0.50, 0.75 and 1.0 wt%; respectively. Finally, total organic carbon (TOC) in the treated water samples reported 100, 28, 11, 9, 10, 13 mg L−1 at control, 0.25, 0.50, 0.75 and 1.0 wt%, respectively. This study can be a preliminary to further studies that accommodate industry-like conditions to help decrease the gap between ideal laboratory setups and harsh real life conditions to fully optimize and exploit the advantages of ceramic membranes in oil-water separation.
AB - Produced water, a by-product generated from the oil and gas extraction processes, represents a major challenge in the oil and gas industry as it is generally characterized with a very high salinity and oil content. Currently used ceramic membranes for oil-water separation suffer from the low water flux in spite of their several distinctive advantages. To overcome this limitation and to increase the water flux and oil rejection, commercial ceramic TiO2 membranes were dip coated with silica (SiO2) nanoparticles at different concentrations of 0.25, 0.50, 0.75, and 1.0 wt %. Coated membranes were characterized using scanning electron microscopy (SEM), energy-dispersive x-ray sSpectroscopy (EDS), Fourier-transform infrared spectroscopy (FTIR) and Raman Spectroscopy and contact angle. Results showed that SiO2 nanoparticles were successfully deposited on the surface of the ceramic membranes confirming the dip coating approach. Furthermore, water flux of 817, 2724, 3636, 627, and 1292 L m−2 h−1 (LMH) was reported at control, 0.25, 0.50, 0.75 and 1.0 wt%; respectively. Also, contact angle reported 75°, 50°, 40°, 24°, 0° at control, 0.25, 0.50, 0.75 and 1.0 wt%; respectively. Finally, total organic carbon (TOC) in the treated water samples reported 100, 28, 11, 9, 10, 13 mg L−1 at control, 0.25, 0.50, 0.75 and 1.0 wt%, respectively. This study can be a preliminary to further studies that accommodate industry-like conditions to help decrease the gap between ideal laboratory setups and harsh real life conditions to fully optimize and exploit the advantages of ceramic membranes in oil-water separation.
KW - Ceramic membranes
KW - Dip-coating
KW - Oil rejection
KW - Produced water
KW - SiO
UR - http://www.scopus.com/inward/record.url?scp=85099627264&partnerID=8YFLogxK
U2 - 10.1016/j.chemosphere.2021.129684
DO - 10.1016/j.chemosphere.2021.129684
M3 - Article
C2 - 33486347
AN - SCOPUS:85099627264
SN - 0045-6535
VL - 273
JO - Chemosphere
JF - Chemosphere
M1 - 129684
ER -