TY - JOUR
T1 - Preparation and Characterization of Shiitake Mushroom-Based Activated Carbon with High Adsorption Capacity
AU - Sun, Zhiwei
AU - Srinivasakannan, C.
AU - Liang, Jinsheng
AU - Duan, Xinhui
N1 - Funding Information:
Acknowledgements This work was supported by the National Natural Science Foundation of China (51641403/E0418).
Publisher Copyright:
© 2019, King Fahd University of Petroleum & Minerals.
PY - 2019/6/1
Y1 - 2019/6/1
N2 - The potential of utilizing shiitake mushroom as feed stock for the preparation of activated carbon by chemical activation method with K 2CO 3 was explored. The prepared materials were characterized by thermogravimetric analysis, N 2 adsorption–desorption analysis, scanning electron microscope, Fourier transform infrared spectrometer, X-ray diffraction and Raman spectra. The activation mechanisms were proposed with the aid of thermogravimetric analysis. X-ray diffraction and Raman analysis indicated that the activated carbon was amorphous macroscopically. The influences of activation temperature, mass ratio of K 2CO 3/shiitake mushroom, activation duration, heating rate and material mixed mode on the yield, porosity and surface morphology of the activated carbon were investigated in detail. The synthesized activated carbons was predominantly microporous having a specific surface area of 2330 m2/g, and the optimal process conditions were activation temperature of 800 ∘C, mass ratio of K 2CO 3/shiitake mushroom of 1.5, activation duration of 180 min, heating rate of 5 ∘C/min and mixed mode of impregnation. Addition to high surface area, it also exhibited a high iodine number adsorption capacity of 1432 mg/g and methylene blue adsorption capacity of 872 mg/g, which are far higher than the adsorption capacities reported in the open literature. These results demonstrate that the synthesized activated carbon could be utilized for variety of industrial applications.
AB - The potential of utilizing shiitake mushroom as feed stock for the preparation of activated carbon by chemical activation method with K 2CO 3 was explored. The prepared materials were characterized by thermogravimetric analysis, N 2 adsorption–desorption analysis, scanning electron microscope, Fourier transform infrared spectrometer, X-ray diffraction and Raman spectra. The activation mechanisms were proposed with the aid of thermogravimetric analysis. X-ray diffraction and Raman analysis indicated that the activated carbon was amorphous macroscopically. The influences of activation temperature, mass ratio of K 2CO 3/shiitake mushroom, activation duration, heating rate and material mixed mode on the yield, porosity and surface morphology of the activated carbon were investigated in detail. The synthesized activated carbons was predominantly microporous having a specific surface area of 2330 m2/g, and the optimal process conditions were activation temperature of 800 ∘C, mass ratio of K 2CO 3/shiitake mushroom of 1.5, activation duration of 180 min, heating rate of 5 ∘C/min and mixed mode of impregnation. Addition to high surface area, it also exhibited a high iodine number adsorption capacity of 1432 mg/g and methylene blue adsorption capacity of 872 mg/g, which are far higher than the adsorption capacities reported in the open literature. These results demonstrate that the synthesized activated carbon could be utilized for variety of industrial applications.
KW - Activated carbon
KW - Activation mechanisms
KW - Adsorption capacity
KW - K CO
KW - Shiitake mushroom
KW - Specific surface area
UR - http://www.scopus.com/inward/record.url?scp=85066485834&partnerID=8YFLogxK
U2 - 10.1007/s13369-019-03746-5
DO - 10.1007/s13369-019-03746-5
M3 - Article
AN - SCOPUS:85066485834
SN - 2193-567X
VL - 44
SP - 5443
EP - 5456
JO - Arabian Journal for Science and Engineering
JF - Arabian Journal for Science and Engineering
IS - 6
ER -