TY - JOUR
T1 - Porous organic polymer composites as surging catalysts for visible-light-driven chemical transformations and pollutant degradation
AU - Chakraborty, Jeet
AU - Nath, Ipsita
AU - Song, Shaoxian
AU - Mohamed, Sharmarke
AU - Khan, Anish
AU - Heynderickx, Philippe M.
AU - Verpoort, Francis Walter C.
N1 - Funding Information:
The authors would like to acknowledge State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology . F.V. acknowledges the support from the Tomsk Polytechnic University Competitiveness Enhancement Program grant . Dr. Jeet Chakraborty obtained his MSc in Chemistry from Indian Institute of Technology, Kanpur, India. He received his PhD from the Laboratory of Organometallics Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology (WHUT), China on photocatalytic porous organic polymers under supervision of Prof. Francis Verpoort. He was employed as a researcher at the Centre for Environmental and Energy Research, Ghent University Global Campus, Korea following his PhD. He is currently a postdoctoral researcher at WHUT working in collaboration with Prof. Francis Verpoort and Prof. Shaoxian Song, where he works on design and synthesis of novel porous organic polymers for advanced applications. Dr. Ipsita Nath received her MSc from Indian Institute of Technology, Hyderabad, India. She got her PhD degree from the Laboratory of Organometallics Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology (WHUT), China on photocatalytic porous organic polymers for environmental applications under supervision of Prof. Francis Verpoort. After her PhD, she joined the Centre for Environmental and Energy Research, Ghent University Global Campus, Korea as a researcher. She is currently a postdoctoral researcher at WHUT working in collaboration with Prof. Francis Verpoort and Prof. Gaoke Zhang. Her present research interest include design and synthesis of photoactive porous organic polymers for catalysis and energy applications. Dr. Sharmarke Mohamed received his PhD in 2011 from UCL under the supervision of Prof. Sarah L. Price and Prof. Derek Tocher. He possesses interdisciplinary research expertise in the domains of materials chemistry, solid-state particle engineering, computational materials modelling and mechanochemical conversion of solid products under ‘green’ solvent-free conditions. Following his PhD, he took up a post-doctoral research scientist position at Zentiva, (the global generics drug manufacturing business of Sanofi). Whilst at Zentiva, he applied his unique interdisciplinary skills in materials science to discover and synthesize the solid forms of a range of proprietary crystal forms of active pharmaceutical ingredients. His efforts led to the award of 3 process patents for discoveries related to methods for the synthesis of crystal forms of active pharmaceutical ingredients with enhanced physicochemical properties. Since 2014, he serves as an Assistant Professor of Chemistry at Khalifa University, where he has taken the lead in establishing a Green Chemistry and Materials Modelling Laboratory (GCMM), and has played a vital role in strengthening the fabric of chemical research at the university. Dr. Anish Khan is Assistant Professor at Chemistry Department, Centre of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah, Saudi Arabia. Completed his Ph.D. in 2010 from Aligarh Muslim University, India and Postdoc from University Sains Malaysia (USM) in 2010. Published more than 115 research articles, 16 book chapters, 6 books and 15 books are in progress with international Publishers. Field of specialization is polymer nano composite / cation-exchanger / chemical sensor / microbiosensor / nanotechnology, and application of nano materials in electroanalytical chemistry, material chemistry, ion-exchange chromatography and electro-analytical chemistry, dealing with the synthesis, characterization and derivatization of inorganic ion-exchanger by the incorporation of electrically conducting polymers Philippe M. Heynderickx (1980, Belgium) received his PhD in Chemical Engineering and Technology from Ghent University in 2009 under the guidance of Prof. Dr. ir. Guy B. Marin. From 2015, he is professor at Ghent University Global Campus (South Korea) and his current work is focused on the modelling of chemical and physical processes and the mathematical treatment of experimental data from heterogeneous catalysis. He is (co-)author of 28 publications in high-impact journals. He received the Young Scientist Award on the 14th International Congress on Catalysis (ICC) in Seoul, Korea (2008). Prof. Francis Verpoort received his DPhil from Ghent University in 1996. In 1998, he became professor at the same university. In 2004, he founded a spin-off company of Ghent University based on (latent) ruthenium olefin metathesis catalysts. In 2008, he became an Editor of Applied Organometallic Chemistry. Currently, next to full professor of Ghent University, he is a Chair Professor at State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology, China). He published more the 300 articles, several chapters of books and has more then 20 patents. He received several Honoree Degrees and his main research interests concern the structure and mechanisms of organometallic material chemistry, homogeneous and heterogeneous catalysis, MOFs and MOPs, Porous organic Polymers (POPs), water splitting, olefin metathesis and its applications in fine chemicals and polymers, CO 2 conversion, polymers. A particular specialism is the application of MOFs, POPs for environment, water purification and downstream upgrading applications.
Funding Information:
The authors would like to acknowledge State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology. F.V. acknowledges the support from the Tomsk Polytechnic University Competitiveness Enhancement Program grant.
Publisher Copyright:
© 2019
PY - 2019/12
Y1 - 2019/12
N2 - The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field.
AB - The promising aspect of photocatalysis to effectively utilize the abundant solar irradiation for promoting various chemical reactions and environmental remediation at greener, low-energy demanding conditions resulted in the recent surge in this research field. In this review, the synthesis and structure-property relationships of photoactive porous organic polymers (POPs) followed by their environmentally benign applications including various chemical transformations and decontamination of pollutants involving key intermediate reactive species have been critically discussed. The conditions required to generate these active species such as photo-generated electron and hole pair, singlet oxygen, superoxide, organic radical, etc. and their different quenching pathways are initially explained to clearly portray the favourable settings necessary for efficient POP-photocatalysis. This introductory discussion is further extrapolated to systematically illustrate the structure-application correlation of every visible-light-responsive POPs reported to date. The mechanisms adapted by POPs for photocatalytic organic reactions and degradation of wastewater pollutants have been comprehensively depicted. Initial discussion on reactive species is envisioned to provide a clear grasp on these later-explained mechanistic pathways. The review is finally concluded by crucially explaining the existing limitations and future development prospects of this field.
KW - HOMO-LUMO
KW - Photocatalysis environmental remediation
KW - Porous organic polymers
KW - Reactive intermediate species
UR - https://www.scopus.com/pages/publications/85072851090
U2 - 10.1016/j.jphotochemrev.2019.100319
DO - 10.1016/j.jphotochemrev.2019.100319
M3 - Review article
AN - SCOPUS:85072851090
SN - 1389-5567
VL - 41
JO - Journal of Photochemistry and Photobiology C: Photochemistry Reviews
JF - Journal of Photochemistry and Photobiology C: Photochemistry Reviews
M1 - 100319
ER -
