Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst active in hydrogenation of xylose

Dinesh Kumar Mishra; Aasif Asharaf Dabbawala; Jin Soo Hwang

doi:10.1016/j.catcom.2013.07.002

Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst active in hydrogenation of xylose

Dinesh Kumar Mishra, Aasif Asharaf Dabbawala, Jin Soo Hwang

Korea Research Institute of Chemical Technology (KRICT)

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst is evaluated first time in selective hydrogenation of xylose to xylitol. The catalyst Ru/PSN is characterized by different techniques such as X-ray powder diffraction, transmission electron microscopy and CO chemisorption. To develop our understanding for the activity of catalyst Ru/PSN, xylose hydrogenation experiments were carried out using catalyst of Ru/PSN with different ruthenium loading (from 1.0% to 3.0%), at different temperatures (from 100 to 140 C) and hydrogen pressures (from 30 to 55 bar). For deactivation test, the catalyst of Ru/PSN recovered from the product solution was reused up to the four times.

Original language	British English
Pages (from-to)	52-55
Number of pages	4
Journal	Catalysis Communications
Volume	41
DOIs	https://doi.org/10.1016/j.catcom.2013.07.002
State	Published - 2013

Keywords

Hydrogenation
Polymer
Ruthenium nanoparticles
Xylitol
Xylose

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10.1016/j.catcom.2013.07.002

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@article{9d02fc97020849708c0204534cc1ced5,

title = "Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst active in hydrogenation of xylose",

abstract = "Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst is evaluated first time in selective hydrogenation of xylose to xylitol. The catalyst Ru/PSN is characterized by different techniques such as X-ray powder diffraction, transmission electron microscopy and CO chemisorption. To develop our understanding for the activity of catalyst Ru/PSN, xylose hydrogenation experiments were carried out using catalyst of Ru/PSN with different ruthenium loading (from 1.0% to 3.0%), at different temperatures (from 100 to 140 C) and hydrogen pressures (from 30 to 55 bar). For deactivation test, the catalyst of Ru/PSN recovered from the product solution was reused up to the four times.",

keywords = "Hydrogenation, Polymer, Ruthenium nanoparticles, Xylitol, Xylose",

author = "Mishra, {Dinesh Kumar} and Dabbawala, {Aasif Asharaf} and Hwang, {Jin Soo}",

note = "Funding Information: This work was supported by the Institutional Research Program of KRICT (SI-1201) and by a grant ( B551179-10-03-00 ) from the cooperative R. & D. Program funded by the Korea Research Council Industrial Science and Technology , Republic of Korea. ",

year = "2013",

doi = "10.1016/j.catcom.2013.07.002",

language = "British English",

volume = "41",

pages = "52--55",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst active in hydrogenation of xylose

AU - Mishra, Dinesh Kumar

AU - Dabbawala, Aasif Asharaf

AU - Hwang, Jin Soo

N1 - Funding Information: This work was supported by the Institutional Research Program of KRICT (SI-1201) and by a grant ( B551179-10-03-00 ) from the cooperative R. & D. Program funded by the Korea Research Council Industrial Science and Technology , Republic of Korea.

PY - 2013

Y1 - 2013

N2 - Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst is evaluated first time in selective hydrogenation of xylose to xylitol. The catalyst Ru/PSN is characterized by different techniques such as X-ray powder diffraction, transmission electron microscopy and CO chemisorption. To develop our understanding for the activity of catalyst Ru/PSN, xylose hydrogenation experiments were carried out using catalyst of Ru/PSN with different ruthenium loading (from 1.0% to 3.0%), at different temperatures (from 100 to 140 C) and hydrogen pressures (from 30 to 55 bar). For deactivation test, the catalyst of Ru/PSN recovered from the product solution was reused up to the four times.

AB - Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst is evaluated first time in selective hydrogenation of xylose to xylitol. The catalyst Ru/PSN is characterized by different techniques such as X-ray powder diffraction, transmission electron microscopy and CO chemisorption. To develop our understanding for the activity of catalyst Ru/PSN, xylose hydrogenation experiments were carried out using catalyst of Ru/PSN with different ruthenium loading (from 1.0% to 3.0%), at different temperatures (from 100 to 140 C) and hydrogen pressures (from 30 to 55 bar). For deactivation test, the catalyst of Ru/PSN recovered from the product solution was reused up to the four times.

KW - Hydrogenation

KW - Polymer

KW - Ruthenium nanoparticles

KW - Xylitol

KW - Xylose

UR - http://www.scopus.com/inward/record.url?scp=84880885461&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2013.07.002

DO - 10.1016/j.catcom.2013.07.002

M3 - Article

AN - SCOPUS:84880885461

SN - 1566-7367

VL - 41

SP - 52

EP - 55

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Poly (styrene-co-divinylbenzene) amine functionalized polymer supported ruthenium nanoparticles catalyst active in hydrogenation of xylose

Abstract

Keywords

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