Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Limin Ren; Qiang Guo; Marat Orazov; Dandan Xu; Dorothea Politi; Prashant Kumar; Saeed M. Alhassan; K. Andre Mkhoyan; Dimitrios Sidiras; Mark E. Davis; Michael Tsapatsis

doi:10.1002/cctc.201600120

Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Limin Ren
, Qiang Guo
, Marat Orazov
, Dandan Xu
, Dorothea Politi
, Prashant Kumar
, Saeed M. Alhassan
, K. Andre Mkhoyan
, Dimitrios Sidiras
, Mark E. Davis
, Michael Tsapatsis

Chemical and Petroleum Engineering

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.

Original language	British English
Pages (from-to)	1274-1278
Number of pages	5
Journal	ChemCatChem
Volume	8
Issue number	7
DOIs	https://doi.org/10.1002/cctc.201600120
State	Published - 6 Apr 2016

Keywords

isomerization
layered materials
Lewis acids
solid-state-exchange
zeolites

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@article{255cafc805704390ad8f10fed1fb09d2,

title = "Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst",

abstract = "Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.",

keywords = "isomerization, layered materials, Lewis acids, solid-state-exchange, zeolites",

author = "Limin Ren and Qiang Guo and Marat Orazov and Dandan Xu and Dorothea Politi and Prashant Kumar and Alhassan, \{Saeed M.\} and Mkhoyan, \{K. Andre\} and Dimitrios Sidiras and Davis, \{Mark E.\} and Michael Tsapatsis",

note = "Funding Information: This work was supported as part of the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award DE-SC0001004. Q.G.'s postdoctoral fellowship was partially supported by the Petroleum Institute of Abu Dhabi. Publisher Copyright: {\textcopyright} 2016 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2016",

month = apr,

day = "6",

doi = "10.1002/cctc.201600120",

language = "British English",

volume = "8",

pages = "1274--1278",

journal = "ChemCatChem",

issn = "1867-3880",

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TY - JOUR

T1 - Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

AU - Ren, Limin

AU - Guo, Qiang

AU - Orazov, Marat

AU - Xu, Dandan

AU - Politi, Dorothea

AU - Kumar, Prashant

AU - Alhassan, Saeed M.

AU - Mkhoyan, K. Andre

AU - Sidiras, Dimitrios

AU - Davis, Mark E.

AU - Tsapatsis, Michael

N1 - Funding Information: This work was supported as part of the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award DE-SC0001004. Q.G.'s postdoctoral fellowship was partially supported by the Petroleum Institute of Abu Dhabi. Publisher Copyright: © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2016/4/6

Y1 - 2016/4/6

N2 - Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.

AB - Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.

KW - isomerization

KW - layered materials

KW - Lewis acids

KW - solid-state-exchange

KW - zeolites

UR - https://www.scopus.com/pages/publications/84978009881

U2 - 10.1002/cctc.201600120

DO - 10.1002/cctc.201600120

M3 - Article

AN - SCOPUS:84978009881

SN - 1867-3880

VL - 8

SP - 1274

EP - 1278

JO - ChemCatChem

JF - ChemCatChem

IS - 7

ER -

Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

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Keywords

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