Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2,5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO 2 nanoparticles

Sedat Yurdakal; Bilge Sina Tek; Oǧuzhan Alagöz; Vincenzo Augugliaro; Vittorio Loddo; Giovanni Palmisano; Leonardo Palmisano

doi:10.1021/sc300142a

Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2,5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO ₂ nanoparticles

Sedat Yurdakal, Bilge Sina Tek, Oǧuzhan Alagöz, Vincenzo Augugliaro, Vittorio Loddo, Giovanni Palmisano, Leonardo Palmisano

Chemical and Petroleum Engineering

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118 Scopus citations

Abstract

5-(Hydroxymethyl)-2-furaldehyde (HMF) was selectively oxidized to 2,5-furandicarbaldehyde (FDC) in aqueous medium by using home-prepared (HP) anatase, rutile, and brookite TiO₂ nanoparticles. HP samples were prepared via a solgel method by using TiCl₄ as the TiO₂ precursor. Commercial TiO₂ catalysts were also used for comparison. All samples were characterized by BET specific surface area, XRD, TGA, and SEM, and the reactivity results showed that HP catalysts are predominantly amorphous and give rise to selectivities toward FDC more than twice that of commercial and well-crystallized catalysts.

Original language	British English
Pages (from-to)	456-461
Number of pages	6
Journal	ACS Sustainable Chemistry and Engineering
Volume	1
Issue number	5
DOIs	https://doi.org/10.1021/sc300142a
State	Published - 6 May 2013

Keywords

2,5-Furandicarbaldehyde
5-(Hydroxymethyl)-2-furaldehyde
Photocatalytic synthesis
Selective oxidation
TiO

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10.1021/sc300142a

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title = "Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2,5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO 2 nanoparticles",

abstract = "5-(Hydroxymethyl)-2-furaldehyde (HMF) was selectively oxidized to 2,5-furandicarbaldehyde (FDC) in aqueous medium by using home-prepared (HP) anatase, rutile, and brookite TiO2 nanoparticles. HP samples were prepared via a solgel method by using TiCl4 as the TiO2 precursor. Commercial TiO2 catalysts were also used for comparison. All samples were characterized by BET specific surface area, XRD, TGA, and SEM, and the reactivity results showed that HP catalysts are predominantly amorphous and give rise to selectivities toward FDC more than twice that of commercial and well-crystallized catalysts.",

keywords = "2,5-Furandicarbaldehyde, 5-(Hydroxymethyl)-2-furaldehyde, Photocatalytic synthesis, Selective oxidation, TiO",

author = "Sedat Yurdakal and Tek, {Bilge Sina} and Oǧuzhan Alag{\"o}z and Vincenzo Augugliaro and Vittorio Loddo and Giovanni Palmisano and Leonardo Palmisano",

year = "2013",

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doi = "10.1021/sc300142a",

language = "British English",

volume = "1",

pages = "456--461",

journal = "ACS Sustainable Chemistry and Engineering",

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Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2,5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO ₂ nanoparticles. / Yurdakal, Sedat; Tek, Bilge Sina; Alagöz, Oǧuzhan et al.
In: ACS Sustainable Chemistry and Engineering, Vol. 1, No. 5, 06.05.2013, p. 456-461.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2,5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO 2 nanoparticles

AU - Yurdakal, Sedat

AU - Tek, Bilge Sina

AU - Alagöz, Oǧuzhan

AU - Augugliaro, Vincenzo

AU - Loddo, Vittorio

AU - Palmisano, Giovanni

AU - Palmisano, Leonardo

PY - 2013/5/6

Y1 - 2013/5/6

N2 - 5-(Hydroxymethyl)-2-furaldehyde (HMF) was selectively oxidized to 2,5-furandicarbaldehyde (FDC) in aqueous medium by using home-prepared (HP) anatase, rutile, and brookite TiO2 nanoparticles. HP samples were prepared via a solgel method by using TiCl4 as the TiO2 precursor. Commercial TiO2 catalysts were also used for comparison. All samples were characterized by BET specific surface area, XRD, TGA, and SEM, and the reactivity results showed that HP catalysts are predominantly amorphous and give rise to selectivities toward FDC more than twice that of commercial and well-crystallized catalysts.

AB - 5-(Hydroxymethyl)-2-furaldehyde (HMF) was selectively oxidized to 2,5-furandicarbaldehyde (FDC) in aqueous medium by using home-prepared (HP) anatase, rutile, and brookite TiO2 nanoparticles. HP samples were prepared via a solgel method by using TiCl4 as the TiO2 precursor. Commercial TiO2 catalysts were also used for comparison. All samples were characterized by BET specific surface area, XRD, TGA, and SEM, and the reactivity results showed that HP catalysts are predominantly amorphous and give rise to selectivities toward FDC more than twice that of commercial and well-crystallized catalysts.

KW - 2,5-Furandicarbaldehyde

KW - 5-(Hydroxymethyl)-2-furaldehyde

KW - Photocatalytic synthesis

KW - Selective oxidation

KW - TiO

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DO - 10.1021/sc300142a

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JO - ACS Sustainable Chemistry and Engineering

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ER -

Photocatalytic selective oxidation of 5-(hydroxymethyl)-2-furaldehyde to 2,5-furandicarbaldehyde in water by using anatase, rutile, and brookite TiO ₂ nanoparticles

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Keywords

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