One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines

Ismail Ibrahem; Henrik Sundén; Ramon Rios; Gui Ling Zhao; Armando Córdova

doi:10.2533/chimia.2007.219

One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines

Ismail Ibrahem, Henrik Sundén, Ramon Rios, Gui Ling Zhao, Armando Córdova

Chemistry

Arrhenius Laboratory

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A simple catalytic racemic synthesis of benzopyranes, benzothiopyranes and 1,2-dihydroquinolines is presented. The organocatalytic domino reactions between 2-heteroatom substituted aldehyde derivatives and α,β-unsaturated aldehydes or α,β-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding products in good to high yields.

Original language	British English
Pages (from-to)	219-223
Number of pages	5
Journal	Chimia
Volume	61
Issue number	5
DOIs	https://doi.org/10.2533/chimia.2007.219
State	Published - 2007

Keywords

Asymmetric synthesis
Organocatalytic domino reactions
Pyrrolidine

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10.2533/chimia.2007.219

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abstract = "A simple catalytic racemic synthesis of benzopyranes, benzothiopyranes and 1,2-dihydroquinolines is presented. The organocatalytic domino reactions between 2-heteroatom substituted aldehyde derivatives and α,β-unsaturated aldehydes or α,β-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding products in good to high yields.",

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author = "Ismail Ibrahem and Henrik Sund{\'e}n and Ramon Rios and Zhao, {Gui Ling} and Armando C{\'o}rdova",

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T1 - One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines

AU - Ibrahem, Ismail

AU - Sundén, Henrik

AU - Rios, Ramon

AU - Zhao, Gui Ling

AU - Córdova, Armando

PY - 2007

Y1 - 2007

N2 - A simple catalytic racemic synthesis of benzopyranes, benzothiopyranes and 1,2-dihydroquinolines is presented. The organocatalytic domino reactions between 2-heteroatom substituted aldehyde derivatives and α,β-unsaturated aldehydes or α,β-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding products in good to high yields.

AB - A simple catalytic racemic synthesis of benzopyranes, benzothiopyranes and 1,2-dihydroquinolines is presented. The organocatalytic domino reactions between 2-heteroatom substituted aldehyde derivatives and α,β-unsaturated aldehydes or α,β-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding products in good to high yields.

KW - Asymmetric synthesis

KW - Organocatalytic domino reactions

KW - Pyrrolidine

UR - http://www.scopus.com/inward/record.url?scp=34250714916&partnerID=8YFLogxK

U2 - 10.2533/chimia.2007.219

DO - 10.2533/chimia.2007.219

M3 - Article

AN - SCOPUS:34250714916

SN - 0009-4293

VL - 61

SP - 219

EP - 223

JO - Chimia

JF - Chimia

IS - 5

ER -

One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines

Abstract

Keywords

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