Abstract
A fine line: The generation of significant positive nonlinear effects in asymmetric amino acid catalysis under homogeneous conditions, which can be explained by the model for cooperative catalytic stereoselective pathways, is reported. The addition of an achiral aldehyde generated the multiple interconnected stereoselective catalytic network.
| Original language | British English |
|---|---|
| Pages (from-to) | 13935-13940 |
| Number of pages | 6 |
| Journal | Chemistry - A European Journal |
| Volume | 16 |
| Issue number | 47 |
| DOIs | |
| State | Published - 17 Dec 2010 |
Keywords
- amino acids
- asymmetric catalysis
- density functional calculations
- enantioselectivity
- nonlinear effects