Nonlinear effects in asymmetric amino acid catalysis by multiple interconnected stereoselective catalytic networks

Ramon Rios, Patric Schyman, Henrik Sundén, Gui Ling Zhao, Farman Ullah, Li Jun Chen, Aatto Laaksonen, Armando Còrdova

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

A fine line: The generation of significant positive nonlinear effects in asymmetric amino acid catalysis under homogeneous conditions, which can be explained by the model for cooperative catalytic stereoselective pathways, is reported. The addition of an achiral aldehyde generated the multiple interconnected stereoselective catalytic network.

Original languageBritish English
Pages (from-to)13935-13940
Number of pages6
JournalChemistry - A European Journal
Volume16
Issue number47
DOIs
StatePublished - 17 Dec 2010

Keywords

  • amino acids
  • asymmetric catalysis
  • density functional calculations
  • enantioselectivity
  • nonlinear effects

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