Non-petrochemical surfactant for enhanced oil recovery

S. Majidaie, M. Mushtaq, I. M. Tan, B. Demiral, S. Y. Lee

    Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

    13 Scopus citations

    Abstract

    A new sulfonate surfactant from non-edible vegetable oils is developed. The sulfonate surfactant was synthesized from C16-18 fatty acid and evaluated for stability, Interfacial Tension (IFT) and core flooding experiments for its capability to enhance oil recovery. The feedstock is composed mostly of unsaturated fatty acid derived from jatropha curcas oil which can be converted to fatty acid methyl ester. The methyl ester is epoxidized and hydrolyzed to hydroxyl groups, which subsequently were sulfonated to form a product named Methyl Ester Sulfonates (MES). The performance of the synthesized surfactant was studied for its stability, IFT and core flooding experiments. The stability shows that surfactant solution in produced water is clear and free of precipitation. Based on IFT experiments optimum surfactant concentration is 1 wt% which resulted in a lowest possible IFT of 0.19 mN/m in the presence of Na2CO3 as alkali. By conducting a displacement test, an improvement in oil recovery is observed. Surfactant floods perform to test how effectively a surfactant formulation can recover oil on tertiary oil recovery. The results confirmed that there is a possibility of developing new surfactants from vegetable oils. It can obviate the need for using petrochemicals substances in synthesizing surfactants.

    Original languageBritish English
    Title of host publicationSociety of Petroleum Engineers - SPE EOR Conference at Oil and Gas West Asia 2012, OGWA - EOR
    Subtitle of host publicationBuilding Towards Sustainable Growth
    Pages161-168
    Number of pages8
    StatePublished - 2012
    EventSPE EOR Conference at Oil and Gas West Asia 2012 - EOR: Building Towards Sustainable Growth, OGWA - Muscat, Oman
    Duration: 16 Apr 201218 Apr 2012

    Publication series

    NameSociety of Petroleum Engineers - SPE EOR Conference at Oil and Gas West Asia 2012, OGWA - EOR: Building Towards Sustainable Growth
    Volume1

    Conference

    ConferenceSPE EOR Conference at Oil and Gas West Asia 2012 - EOR: Building Towards Sustainable Growth, OGWA
    Country/TerritoryOman
    CityMuscat
    Period16/04/1218/04/12

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