Nanostructured rutile TiO2 for selective photocatalytic oxidation of aromatic alcohols to aldehydes in water

Sedat Yurdakal; Giovanni Palmisano; Vittorio Loddo; Vincenzo Augugliaro; Leonardo Palmisano

doi:10.1021/ja709989e

Nanostructured rutile TiO₂ for selective photocatalytic oxidation of aromatic alcohols to aldehydes in water

Sedat Yurdakal, Giovanni Palmisano, Vittorio Loddo, Vincenzo Augugliaro, Leonardo Palmisano

Chemical and Petroleum Engineering

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425 Scopus citations

Abstract

Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO₂ rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl₄ at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).

Original language	British English
Pages (from-to)	1568-1569
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	5
DOIs	https://doi.org/10.1021/ja709989e
State	Published - 6 Feb 2008

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abstract = "Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).",

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AU - Yurdakal, Sedat

AU - Palmisano, Giovanni

AU - Loddo, Vittorio

AU - Augugliaro, Vincenzo

AU - Palmisano, Leonardo

PY - 2008/2/6

Y1 - 2008/2/6

N2 - Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).

AB - Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).

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Nanostructured rutile TiO₂ for selective photocatalytic oxidation of aromatic alcohols to aldehydes in water

Abstract

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