Abstract
Nanopore generation could be accomplished in thin films of fully alicyclic polyimides derived from an alicyclic dianhydride and diamines. A silylation method for the alicyclic diamines was used to synthesize high molecular weight alicyclic polyimides. Triblock copolyimides were prepared using N-silylated alicyclic diamines, alicyclic dianhydride, and a thermally labile polymer. Nanoporous films of fully alicyclic polyimides were prepared through heating of the copolyimide films to induce thermal degradation of the labile block.
| Original language | British English |
|---|---|
| Pages (from-to) | 1272-1277 |
| Number of pages | 6 |
| Journal | Macromolecular Research |
| Volume | 19 |
| Issue number | 12 |
| DOIs | |
| State | Published - Dec 2011 |
Keywords
- fully alicyclic polyimide
- nanoporous film
- silylation
- triblock copolyimide