Nanoporous thin films of fully alicyclic polyimides

  • Hwan Chul Yu
  • , S. Vijay Kumar
  • , Young Kyu Song
  • , Jiyoung Choi
  • , Kazuaki Kudo
  • , Joong Gon Kim
  • , Se Young Oh
  • , Chan Moon Chung

    Research output: Contribution to journalArticlepeer-review

    10 Scopus citations

    Abstract

    Nanopore generation could be accomplished in thin films of fully alicyclic polyimides derived from an alicyclic dianhydride and diamines. A silylation method for the alicyclic diamines was used to synthesize high molecular weight alicyclic polyimides. Triblock copolyimides were prepared using N-silylated alicyclic diamines, alicyclic dianhydride, and a thermally labile polymer. Nanoporous films of fully alicyclic polyimides were prepared through heating of the copolyimide films to induce thermal degradation of the labile block.

    Original languageBritish English
    Pages (from-to)1272-1277
    Number of pages6
    JournalMacromolecular Research
    Volume19
    Issue number12
    DOIs
    StatePublished - Dec 2011

    Keywords

    • fully alicyclic polyimide
    • nanoporous film
    • silylation
    • triblock copolyimide

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