Abstract
Nanopore generation could be accomplished in thin films of fully alicyclic polyimides derived from an alicyclic dianhydride and diamines. A silylation method for the alicyclic diamines was used to synthesize high molecular weight alicyclic polyimides. Triblock copolyimides were prepared using N-silylated alicyclic diamines, alicyclic dianhydride, and a thermally labile polymer. Nanoporous films of fully alicyclic polyimides were prepared through heating of the copolyimide films to induce thermal degradation of the labile block.
Original language | British English |
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Pages (from-to) | 1272-1277 |
Number of pages | 6 |
Journal | Macromolecular Research |
Volume | 19 |
Issue number | 12 |
DOIs | |
State | Published - Dec 2011 |
Keywords
- fully alicyclic polyimide
- nanoporous film
- silylation
- triblock copolyimide