N-vinylpyrrolidone and ethoxyethyl methacrylate copolymer: Synthesis, characterization and reactivity ratios

S. Vijay Kumar; T. E. Musturappa; S. Prasannakumar; K. M. Mahadevan; B. S. Sherigara

doi:10.1080/10601320701561072

N-vinylpyrrolidone and ethoxyethyl methacrylate copolymer: Synthesis, characterization and reactivity ratios

S. Vijay Kumar
, T. E. Musturappa
, S. Prasannakumar
, K. M. Mahadevan
, B. S. Sherigara

Kuvempu University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Free radical copolymerization of N-vinyl-2-pyrrolidone with 2-ethoxyethyl methacrylates was carried out with 2,2'-azobisisobutyronotrile as an initiator in 1,4-dioxane. The resulting copolymer was characterized by FTIR, H1-NMR and C13-NMR spectroscopic techniques thermal properties of copolymer were determined by DSC and TGA. The reactivity ratios of the monomers were computed by the Fineman-Rose (F-R), Kelen-Tudos (K-T) and extended Kelen-Tudos (EK-T) method at lower conversion, using the data obtained from both FTIR and elemental analysis studies; the results are in good agreement with each other. The average reactivity ratio, Alfrey-Price Q and e values were found to be r1=0.769, r2=0.266 and Q1=0.0859, e1=0.4508, respectively for NVP/EOEMA copolymer. The distribution of monomer sequence along the copolymer chain was calculated using a statistical method based on obtained reactivity ratio. The number average molecular weight and polydispersity were determined by GPC.

Original language	British English
Pages (from-to)	1161-1169
Number of pages	9
Journal	Journal of Macromolecular Science, Part A: Pure and Applied Chemistry
Volume	44
Issue number	11
DOIs	https://doi.org/10.1080/10601320701561072
State	Published - Nov 2007

Keywords

Comonomer sequence and distribution
Ethoxyethyl methacrylate
N-vinylpyrrolidone
Reactivity ratio

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10.1080/10601320701561072

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@article{ef4f33f3b42c4065b6bc2b98d3c6ebd7,

title = "N-vinylpyrrolidone and ethoxyethyl methacrylate copolymer: Synthesis, characterization and reactivity ratios",

abstract = "Free radical copolymerization of N-vinyl-2-pyrrolidone with 2-ethoxyethyl methacrylates was carried out with 2,2'-azobisisobutyronotrile as an initiator in 1,4-dioxane. The resulting copolymer was characterized by FTIR, H1-NMR and C13-NMR spectroscopic techniques thermal properties of copolymer were determined by DSC and TGA. The reactivity ratios of the monomers were computed by the Fineman-Rose (F-R), Kelen-Tudos (K-T) and extended Kelen-Tudos (EK-T) method at lower conversion, using the data obtained from both FTIR and elemental analysis studies; the results are in good agreement with each other. The average reactivity ratio, Alfrey-Price Q and e values were found to be r1=0.769, r2=0.266 and Q1=0.0859, e1=0.4508, respectively for NVP/EOEMA copolymer. The distribution of monomer sequence along the copolymer chain was calculated using a statistical method based on obtained reactivity ratio. The number average molecular weight and polydispersity were determined by GPC.",

keywords = "Comonomer sequence and distribution, Ethoxyethyl methacrylate, N-vinylpyrrolidone, Reactivity ratio",

author = "Kumar, \{S. Vijay\} and Musturappa, \{T. E.\} and S. Prasannakumar and Mahadevan, \{K. M.\} and Sherigara, \{B. S.\}",

note = "Funding Information: One of the authors (VKS) thanks Kuvempu University, Jnana Sahyadri, for awarding a research fellowship.",

year = "2007",

month = nov,

doi = "10.1080/10601320701561072",

language = "British English",

volume = "44",

pages = "1161--1169",

journal = "Journal of Macromolecular Science, Part A: Pure and Applied Chemistry",

issn = "1060-1325",

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number = "11",

}

TY - JOUR

T1 - N-vinylpyrrolidone and ethoxyethyl methacrylate copolymer

T2 - Synthesis, characterization and reactivity ratios

AU - Kumar, S. Vijay

AU - Musturappa, T. E.

AU - Prasannakumar, S.

AU - Mahadevan, K. M.

AU - Sherigara, B. S.

N1 - Funding Information: One of the authors (VKS) thanks Kuvempu University, Jnana Sahyadri, for awarding a research fellowship.

PY - 2007/11

Y1 - 2007/11

N2 - Free radical copolymerization of N-vinyl-2-pyrrolidone with 2-ethoxyethyl methacrylates was carried out with 2,2'-azobisisobutyronotrile as an initiator in 1,4-dioxane. The resulting copolymer was characterized by FTIR, H1-NMR and C13-NMR spectroscopic techniques thermal properties of copolymer were determined by DSC and TGA. The reactivity ratios of the monomers were computed by the Fineman-Rose (F-R), Kelen-Tudos (K-T) and extended Kelen-Tudos (EK-T) method at lower conversion, using the data obtained from both FTIR and elemental analysis studies; the results are in good agreement with each other. The average reactivity ratio, Alfrey-Price Q and e values were found to be r1=0.769, r2=0.266 and Q1=0.0859, e1=0.4508, respectively for NVP/EOEMA copolymer. The distribution of monomer sequence along the copolymer chain was calculated using a statistical method based on obtained reactivity ratio. The number average molecular weight and polydispersity were determined by GPC.

AB - Free radical copolymerization of N-vinyl-2-pyrrolidone with 2-ethoxyethyl methacrylates was carried out with 2,2'-azobisisobutyronotrile as an initiator in 1,4-dioxane. The resulting copolymer was characterized by FTIR, H1-NMR and C13-NMR spectroscopic techniques thermal properties of copolymer were determined by DSC and TGA. The reactivity ratios of the monomers were computed by the Fineman-Rose (F-R), Kelen-Tudos (K-T) and extended Kelen-Tudos (EK-T) method at lower conversion, using the data obtained from both FTIR and elemental analysis studies; the results are in good agreement with each other. The average reactivity ratio, Alfrey-Price Q and e values were found to be r1=0.769, r2=0.266 and Q1=0.0859, e1=0.4508, respectively for NVP/EOEMA copolymer. The distribution of monomer sequence along the copolymer chain was calculated using a statistical method based on obtained reactivity ratio. The number average molecular weight and polydispersity were determined by GPC.

KW - Comonomer sequence and distribution

KW - Ethoxyethyl methacrylate

KW - N-vinylpyrrolidone

KW - Reactivity ratio

UR - https://www.scopus.com/pages/publications/34548303436

U2 - 10.1080/10601320701561072

DO - 10.1080/10601320701561072

M3 - Article

AN - SCOPUS:34548303436

SN - 1060-1325

VL - 44

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EP - 1169

JO - Journal of Macromolecular Science, Part A: Pure and Applied Chemistry

JF - Journal of Macromolecular Science, Part A: Pure and Applied Chemistry

IS - 11

ER -

N-vinylpyrrolidone and ethoxyethyl methacrylate copolymer: Synthesis, characterization and reactivity ratios

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