Mesoporous cubic Ia3d materials for the preparation of fine chemicals: Synthesis of jasminaldehyde

Azhagapillai Prabhu; Muthaiahpillai Palanichamy

doi:10.1016/j.micromeso.2012.09.020

Mesoporous cubic Ia3d materials for the preparation of fine chemicals: Synthesis of jasminaldehyde

Azhagapillai Prabhu
, Muthaiahpillai Palanichamy

Anna University

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The synthesis of mesoporous Al-KIT-6 is synthesized by direct hydrothermal method with different Si/Al ratios (20, 30, 50, 100 and 150) were characterized by XRD, ICP-AES, BET, SEM and HR-TEM. Mesoporous Al-KIT-6 was synthesized from assembly of polymer surfactant micelle as a template in acidic media. Mesoporous Al-KIT-6 was good phase purity from XRD analysis. The HR-TEM picture of Al-KIT-6 (50) showed formation of particles of cubic morphology and SEM images are also shown rod like morphology. α-n-Amylcinnamaldehyde (jasminaldehyde) has been prepared with high selectivity and using low ratios of benzaldehyde/heptanal by means of mesoporous Al-KIT-6 molecular sieves.

Original language	British English
Pages (from-to)	126-131
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	168
DOIs	https://doi.org/10.1016/j.micromeso.2012.09.020
State	Published - 1 Mar 2013

Keywords

1-Heptanal
Al-KIT-6
Benzaldehyde
Jasminaldehyde
Mesoporous cubic ia3d

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10.1016/j.micromeso.2012.09.020

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title = "Mesoporous cubic Ia3d materials for the preparation of fine chemicals: Synthesis of jasminaldehyde",

abstract = "The synthesis of mesoporous Al-KIT-6 is synthesized by direct hydrothermal method with different Si/Al ratios (20, 30, 50, 100 and 150) were characterized by XRD, ICP-AES, BET, SEM and HR-TEM. Mesoporous Al-KIT-6 was synthesized from assembly of polymer surfactant micelle as a template in acidic media. Mesoporous Al-KIT-6 was good phase purity from XRD analysis. The HR-TEM picture of Al-KIT-6 (50) showed formation of particles of cubic morphology and SEM images are also shown rod like morphology. α-n-Amylcinnamaldehyde (jasminaldehyde) has been prepared with high selectivity and using low ratios of benzaldehyde/heptanal by means of mesoporous Al-KIT-6 molecular sieves.",

keywords = "1-Heptanal, Al-KIT-6, Benzaldehyde, Jasminaldehyde, Mesoporous cubic ia3d",

author = "Azhagapillai Prabhu and Muthaiahpillai Palanichamy",

year = "2013",

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doi = "10.1016/j.micromeso.2012.09.020",

language = "British English",

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journal = "Microporous and Mesoporous Materials",

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TY - JOUR

T1 - Mesoporous cubic Ia3d materials for the preparation of fine chemicals

T2 - Synthesis of jasminaldehyde

AU - Prabhu, Azhagapillai

AU - Palanichamy, Muthaiahpillai

PY - 2013/3/1

Y1 - 2013/3/1

N2 - The synthesis of mesoporous Al-KIT-6 is synthesized by direct hydrothermal method with different Si/Al ratios (20, 30, 50, 100 and 150) were characterized by XRD, ICP-AES, BET, SEM and HR-TEM. Mesoporous Al-KIT-6 was synthesized from assembly of polymer surfactant micelle as a template in acidic media. Mesoporous Al-KIT-6 was good phase purity from XRD analysis. The HR-TEM picture of Al-KIT-6 (50) showed formation of particles of cubic morphology and SEM images are also shown rod like morphology. α-n-Amylcinnamaldehyde (jasminaldehyde) has been prepared with high selectivity and using low ratios of benzaldehyde/heptanal by means of mesoporous Al-KIT-6 molecular sieves.

AB - The synthesis of mesoporous Al-KIT-6 is synthesized by direct hydrothermal method with different Si/Al ratios (20, 30, 50, 100 and 150) were characterized by XRD, ICP-AES, BET, SEM and HR-TEM. Mesoporous Al-KIT-6 was synthesized from assembly of polymer surfactant micelle as a template in acidic media. Mesoporous Al-KIT-6 was good phase purity from XRD analysis. The HR-TEM picture of Al-KIT-6 (50) showed formation of particles of cubic morphology and SEM images are also shown rod like morphology. α-n-Amylcinnamaldehyde (jasminaldehyde) has been prepared with high selectivity and using low ratios of benzaldehyde/heptanal by means of mesoporous Al-KIT-6 molecular sieves.

KW - 1-Heptanal

KW - Al-KIT-6

KW - Benzaldehyde

KW - Jasminaldehyde

KW - Mesoporous cubic ia3d

UR - https://www.scopus.com/pages/publications/84868229977

U2 - 10.1016/j.micromeso.2012.09.020

DO - 10.1016/j.micromeso.2012.09.020

M3 - Article

AN - SCOPUS:84868229977

SN - 1387-1811

VL - 168

SP - 126

EP - 131

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Mesoporous cubic Ia3d materials for the preparation of fine chemicals: Synthesis of jasminaldehyde

Abstract

Keywords

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