Merging Organocatalysis with Metals - New Opportunities for Asymmetric Synthesis

Ramon Rios

doi:10.1002/9783527832217.ch10

Merging Organocatalysis with Metals - New Opportunities for Asymmetric Synthesis

Ramon Rios

Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

In this chapter, we focus our attention on the merging of metal chemistry with organocatalysis. The chapter describes the more important approaches using enamine, iminium, and NHC chemistry. From the pioneering works of Cordova and Sairic regarding intra- and intermolecular Tsuji-Trost-type reactions promoted by enamine chemistry since the last cascade reactions, which are able to build several C-C or C-heteroatom with almost perfect stereoselectivity even for spirocompounds.

Original language	British English
Title of host publication	Asymmetric Organocatalysis
Subtitle of host publication	New Strategies, Catalysts, and Opportunities: Volume 1-2
Publisher	wiley
Pages	319-348
Number of pages	30
Volume	1-2
ISBN (Electronic)	9783527832217
ISBN (Print)	9783527351251
DOIs	https://doi.org/10.1002/9783527832217.ch10
State	Published - 1 Jan 2022

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10.1002/9783527832217.ch10

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abstract = "In this chapter, we focus our attention on the merging of metal chemistry with organocatalysis. The chapter describes the more important approaches using enamine, iminium, and NHC chemistry. From the pioneering works of Cordova and Sairic regarding intra- and intermolecular Tsuji-Trost-type reactions promoted by enamine chemistry since the last cascade reactions, which are able to build several C-C or C-heteroatom with almost perfect stereoselectivity even for spirocompounds.",

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AB - In this chapter, we focus our attention on the merging of metal chemistry with organocatalysis. The chapter describes the more important approaches using enamine, iminium, and NHC chemistry. From the pioneering works of Cordova and Sairic regarding intra- and intermolecular Tsuji-Trost-type reactions promoted by enamine chemistry since the last cascade reactions, which are able to build several C-C or C-heteroatom with almost perfect stereoselectivity even for spirocompounds.

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Merging Organocatalysis with Metals - New Opportunities for Asymmetric Synthesis

Abstract

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