Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves

N. Narender; K. Suresh Kumar Reddy; K. V.V. Krishna Mohan; S. J. Kulkarni; K. V. Raghavan

doi:10.1016/S0167-2991(07)81073-1

Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves

N. Narender, K. Suresh Kumar Reddy, K. V.V. Krishna Mohan, S. J. Kulkarni, K. V. Raghavan

Indian Institute of Chemical Technology

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

The oxidation of 2-methyl-naphthalene (2MN) to 2-methyl-1,4-naphthoquinone (2MNQ), vitamin K₃ (menadione) was carried out over MoMCM-41 mesoporous molecular sieve catalyst. The typical reaction run was carried out using acetic acid as a solvent, hydrogen peroxide (H2O2) as an oxidant, in the temperature range of 60-120°C for 2-12 h. The liquid product selectivities to 2-methyl-1,4-naphthoquinone were 85, 80, 81 and 79 percent at 12, 69, 98 and 99 percent conversions of 2MN for the molar ratio of 2MN:H₂O₂ equal to 1:2, 1:4, 1:6 and 1:7 respectively. The effect of the various parameters including reaction temperature, molar ratio of 2MN:H₂O₂, Si/Mo ratio, various catalysts, various solvents, the various molybdenum precursors and amount of catalyst were studied. The selectivity to benzaldehyde was 99 percent at 50 percent conversion of styrene over WMCM-41 mesoporous molecular sieve catalyst.

Original language	British English
Title of host publication	From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
Publisher	Elsevier Inc.
Pages	1877-1883
Number of pages	7
Edition	B
ISBN (Print)	0444530681, 9780444530684
DOIs	https://doi.org/10.1016/S0167-2991(07)81073-1
State	Published - 2007

Publication series

Name	Studies in Surface Science and Catalysis
Number	B
Volume	170
ISSN (Print)	0167-2991

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10.1016/S0167-2991(07)81073-1

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Narender, N., Suresh Kumar Reddy, K., Krishna Mohan, K. V. V., Kulkarni, S. J., & Raghavan, K. V. (2007). Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference (B ed., pp. 1877-1883). (Studies in Surface Science and Catalysis; Vol. 170, No. B). Elsevier Inc.. https://doi.org/10.1016/S0167-2991(07)81073-1

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title = "Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves",

abstract = "The oxidation of 2-methyl-naphthalene (2MN) to 2-methyl-1,4-naphthoquinone (2MNQ), vitamin K3 (menadione) was carried out over MoMCM-41 mesoporous molecular sieve catalyst. The typical reaction run was carried out using acetic acid as a solvent, hydrogen peroxide (H2O2) as an oxidant, in the temperature range of 60-120°C for 2-12 h. The liquid product selectivities to 2-methyl-1,4-naphthoquinone were 85, 80, 81 and 79 percent at 12, 69, 98 and 99 percent conversions of 2MN for the molar ratio of 2MN:H2O2 equal to 1:2, 1:4, 1:6 and 1:7 respectively. The effect of the various parameters including reaction temperature, molar ratio of 2MN:H2O2, Si/Mo ratio, various catalysts, various solvents, the various molybdenum precursors and amount of catalyst were studied. The selectivity to benzaldehyde was 99 percent at 50 percent conversion of styrene over WMCM-41 mesoporous molecular sieve catalyst.",

author = "N. Narender and {Suresh Kumar Reddy}, K. and {Krishna Mohan}, {K. V.V.} and Kulkarni, {S. J.} and Raghavan, {K. V.}",

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Narender, N, Suresh Kumar Reddy, K, Krishna Mohan, KVV, Kulkarni, SJ & Raghavan, KV 2007, Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves. in From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B edn, Studies in Surface Science and Catalysis, no. B, vol. 170, Elsevier Inc., pp. 1877-1883. https://doi.org/10.1016/S0167-2991(07)81073-1

Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves. / Narender, N.; Suresh Kumar Reddy, K.; Krishna Mohan, K. V.V. et al.
From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B. ed. Elsevier Inc., 2007. p. 1877-1883 (Studies in Surface Science and Catalysis; Vol. 170, No. B).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves

AU - Narender, N.

AU - Suresh Kumar Reddy, K.

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AU - Kulkarni, S. J.

AU - Raghavan, K. V.

PY - 2007

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N2 - The oxidation of 2-methyl-naphthalene (2MN) to 2-methyl-1,4-naphthoquinone (2MNQ), vitamin K3 (menadione) was carried out over MoMCM-41 mesoporous molecular sieve catalyst. The typical reaction run was carried out using acetic acid as a solvent, hydrogen peroxide (H2O2) as an oxidant, in the temperature range of 60-120°C for 2-12 h. The liquid product selectivities to 2-methyl-1,4-naphthoquinone were 85, 80, 81 and 79 percent at 12, 69, 98 and 99 percent conversions of 2MN for the molar ratio of 2MN:H2O2 equal to 1:2, 1:4, 1:6 and 1:7 respectively. The effect of the various parameters including reaction temperature, molar ratio of 2MN:H2O2, Si/Mo ratio, various catalysts, various solvents, the various molybdenum precursors and amount of catalyst were studied. The selectivity to benzaldehyde was 99 percent at 50 percent conversion of styrene over WMCM-41 mesoporous molecular sieve catalyst.

AB - The oxidation of 2-methyl-naphthalene (2MN) to 2-methyl-1,4-naphthoquinone (2MNQ), vitamin K3 (menadione) was carried out over MoMCM-41 mesoporous molecular sieve catalyst. The typical reaction run was carried out using acetic acid as a solvent, hydrogen peroxide (H2O2) as an oxidant, in the temperature range of 60-120°C for 2-12 h. The liquid product selectivities to 2-methyl-1,4-naphthoquinone were 85, 80, 81 and 79 percent at 12, 69, 98 and 99 percent conversions of 2MN for the molar ratio of 2MN:H2O2 equal to 1:2, 1:4, 1:6 and 1:7 respectively. The effect of the various parameters including reaction temperature, molar ratio of 2MN:H2O2, Si/Mo ratio, various catalysts, various solvents, the various molybdenum precursors and amount of catalyst were studied. The selectivity to benzaldehyde was 99 percent at 50 percent conversion of styrene over WMCM-41 mesoporous molecular sieve catalyst.

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SN - 0444530681

SN - 9780444530684

T3 - Studies in Surface Science and Catalysis

SP - 1877

EP - 1883

BT - From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference

PB - Elsevier Inc.

ER -

Narender N, Suresh Kumar Reddy K, Krishna Mohan KVV, Kulkarni SJ, Raghavan KV. Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference. B ed. Elsevier Inc. 2007. p. 1877-1883. (Studies in Surface Science and Catalysis; B). doi: 10.1016/S0167-2991(07)81073-1

Liquid phase oxidation reactions over MoMCM-41 and WMCM- 41molecular sieves

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