Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures

Bridgid Chin Lai Fui; Suzana Yusup; Ahmed Al Shoaibi; Pravin Kannan; Chandrasekar Srinivasakannan; Shaharin Anwar Sulaiman

doi:10.4028/www.scientific.net/AMM.625.251

Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures

Bridgid Chin Lai Fui, Suzana Yusup, Ahmed Al Shoaibi, Pravin Kannan, Chandrasekar Srinivasakannan, Shaharin Anwar Sulaiman

Chemical and Petroleum Engineering

Universiti Teknologi PETRONAS

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

In this paper, the catalytic co-gasification of rubber seed shell and high density polyethylene mixtures (0.2:0.8 weight ratio of HDPE:RSS) are investigated using a non-isothermal thermogravimetric analysis (TGA) system in a range of heating rates of 10, 20, 30 and 50 K/min within the temperature range of 323-1173 K. The argon gas is supplied at a flowrate of 100 ml/min and the steam is generated from superheater at 383 K. The steam is injected at flowrate of 300 μL/hour into the TGA system. A commercial nickel powder is used as the catalyst for the gasification process. The thermal decomposition behavior and synergistic effect of the HDPE/RSS mixture are investigated. The activation energy, E_A and pre-exponential factor, A are determined based on one step integral method.

Original language	British English
Title of host publication	Process and Advanced Materials Engineering
Editors	Iqbal Ahmed
Pages	251-254
Number of pages	4
ISBN (Electronic)	9783038351818
DOIs	https://doi.org/10.4028/www.scientific.net/AMM.625.251
State	Published - 2014
Event	3rd International Conference on Process Engineering and Advanced Materials, ICPEAM 2014 - Kuala Lumpur, Malaysia Duration: 3 Jun 2014 → 5 Jun 2014

Publication series

Name	Applied Mechanics and Materials
Volume	625
ISSN (Print)	1660-9336
ISSN (Electronic)	1662-7482

Conference

Conference	3rd International Conference on Process Engineering and Advanced Materials, ICPEAM 2014
Country/Territory	Malaysia
City	Kuala Lumpur
Period	3/06/14 → 5/06/14

Keywords

Gasification
High Density Polyethylene (HDPE)
Kinetic Parameters
Nickel catalyst
Rubber Seed Shell (RSS)

Access to Document

10.4028/www.scientific.net/AMM.625.251

Cite this

Lai Fui, B. C., Yusup, S., Shoaibi, A. A., Kannan, P., Srinivasakannan, C., & Sulaiman, S. A. (2014). Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures. In I. Ahmed (Ed.), Process and Advanced Materials Engineering (pp. 251-254). (Applied Mechanics and Materials; Vol. 625). https://doi.org/10.4028/www.scientific.net/AMM.625.251

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title = "Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures",

abstract = "In this paper, the catalytic co-gasification of rubber seed shell and high density polyethylene mixtures (0.2:0.8 weight ratio of HDPE:RSS) are investigated using a non-isothermal thermogravimetric analysis (TGA) system in a range of heating rates of 10, 20, 30 and 50 K/min within the temperature range of 323-1173 K. The argon gas is supplied at a flowrate of 100 ml/min and the steam is generated from superheater at 383 K. The steam is injected at flowrate of 300 μL/hour into the TGA system. A commercial nickel powder is used as the catalyst for the gasification process. The thermal decomposition behavior and synergistic effect of the HDPE/RSS mixture are investigated. The activation energy, EA and pre-exponential factor, A are determined based on one step integral method.",

keywords = "Gasification, High Density Polyethylene (HDPE), Kinetic Parameters, Nickel catalyst, Rubber Seed Shell (RSS)",

author = "{Lai Fui}, {Bridgid Chin} and Suzana Yusup and Shoaibi, {Ahmed Al} and Pravin Kannan and Chandrasekar Srinivasakannan and Sulaiman, {Shaharin Anwar}",

note = "Publisher Copyright: {\textcopyright} 2014 Trans Tech Publications, Switzerland.; 3rd International Conference on Process Engineering and Advanced Materials, ICPEAM 2014 ; Conference date: 03-06-2014 Through 05-06-2014",

year = "2014",

doi = "10.4028/www.scientific.net/AMM.625.251",

language = "British English",

series = "Applied Mechanics and Materials",

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booktitle = "Process and Advanced Materials Engineering",

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Lai Fui, BC, Yusup, S, Shoaibi, AA, Kannan, P, Srinivasakannan, C & Sulaiman, SA 2014, Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures. in I Ahmed (ed.), Process and Advanced Materials Engineering. Applied Mechanics and Materials, vol. 625, pp. 251-254, 3rd International Conference on Process Engineering and Advanced Materials, ICPEAM 2014, Kuala Lumpur, Malaysia, 3/06/14. https://doi.org/10.4028/www.scientific.net/AMM.625.251

Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures. / Lai Fui, Bridgid Chin; Yusup, Suzana; Shoaibi, Ahmed Al et al.
Process and Advanced Materials Engineering. ed. / Iqbal Ahmed. 2014. p. 251-254 (Applied Mechanics and Materials; Vol. 625).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Lai Fui, Bridgid Chin

AU - Yusup, Suzana

AU - Shoaibi, Ahmed Al

AU - Kannan, Pravin

AU - Srinivasakannan, Chandrasekar

AU - Sulaiman, Shaharin Anwar

PY - 2014

Y1 - 2014

N2 - In this paper, the catalytic co-gasification of rubber seed shell and high density polyethylene mixtures (0.2:0.8 weight ratio of HDPE:RSS) are investigated using a non-isothermal thermogravimetric analysis (TGA) system in a range of heating rates of 10, 20, 30 and 50 K/min within the temperature range of 323-1173 K. The argon gas is supplied at a flowrate of 100 ml/min and the steam is generated from superheater at 383 K. The steam is injected at flowrate of 300 μL/hour into the TGA system. A commercial nickel powder is used as the catalyst for the gasification process. The thermal decomposition behavior and synergistic effect of the HDPE/RSS mixture are investigated. The activation energy, EA and pre-exponential factor, A are determined based on one step integral method.

AB - In this paper, the catalytic co-gasification of rubber seed shell and high density polyethylene mixtures (0.2:0.8 weight ratio of HDPE:RSS) are investigated using a non-isothermal thermogravimetric analysis (TGA) system in a range of heating rates of 10, 20, 30 and 50 K/min within the temperature range of 323-1173 K. The argon gas is supplied at a flowrate of 100 ml/min and the steam is generated from superheater at 383 K. The steam is injected at flowrate of 300 μL/hour into the TGA system. A commercial nickel powder is used as the catalyst for the gasification process. The thermal decomposition behavior and synergistic effect of the HDPE/RSS mixture are investigated. The activation energy, EA and pre-exponential factor, A are determined based on one step integral method.

KW - Gasification

KW - High Density Polyethylene (HDPE)

KW - Kinetic Parameters

KW - Nickel catalyst

KW - Rubber Seed Shell (RSS)

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AN - SCOPUS:84914127278

T3 - Applied Mechanics and Materials

SP - 251

EP - 254

BT - Process and Advanced Materials Engineering

A2 - Ahmed, Iqbal

T2 - 3rd International Conference on Process Engineering and Advanced Materials, ICPEAM 2014

Y2 - 3 June 2014 through 5 June 2014

ER -

Kinetic analysis on catalytic co-gasification of rubber seed shell and high density polyethylene mixtures

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Keywords

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