TY - JOUR
T1 - Isatin as a new core in the development of corrosion inhibitors: A comprehensive review
T2 - Journal of Molecular Structure
AU - Verma, D.K.
AU - Sahu, R.
AU - Berdimurodov, E.
AU - Verma, C.
AU - Quraishi, M.A.
AU - Jain, V.K.
AU - Berdimuradov, K.
N1 - Export Date: 11 January 2024; Cited By: 2; Correspondence Address: D.K. Verma; Department of Chemistry, Government Digvijay Autonomous Postgraduate College, Rajnandgaon, Chhattisgarh, 491441, India; email: [email protected]; E. Berdimurodov; Faculty of Chemistry, National University of Uzbekistan, Tashkent, 100034, Uzbekistan; email: [email protected]; CODEN: JMOSB
PY - 2023
Y1 - 2023
N2 - The functioning of organic compounds, especially aromatic heterocyclic compounds, is the most effective and economical method of corrosion inhibition of metallic materials such as iron, aluminum, copper and their alloys. The present review article first describes recent developments in isatin and its derivatives as a new, efficient and green N-heterocyclic class of organic corrosion inhibitors. The molecular structure of isatin and its derivatives are more comfortable for developing the next generation of corrosion inhibitors having the following characteristics: chemically stable, high thermal activity, excellent antibacterial agents, low toxicity, biocompatibility, good water solubility and non-flammable. The anodic and cathodic acts on the metal surface are blocked maximally by the amino functional group of isatin rings. These inhibitors are mixed-type inhibitors as they retard both anodic and cathodic Tafel reactions. In future research, the isatin rings would be modified with the carbo dots, polymers, nanocarriers, ionic liquids, and surfactants, which would be dominant in corrosion inhibition analysis. © 2023 Elsevier B.V.
AB - The functioning of organic compounds, especially aromatic heterocyclic compounds, is the most effective and economical method of corrosion inhibition of metallic materials such as iron, aluminum, copper and their alloys. The present review article first describes recent developments in isatin and its derivatives as a new, efficient and green N-heterocyclic class of organic corrosion inhibitors. The molecular structure of isatin and its derivatives are more comfortable for developing the next generation of corrosion inhibitors having the following characteristics: chemically stable, high thermal activity, excellent antibacterial agents, low toxicity, biocompatibility, good water solubility and non-flammable. The anodic and cathodic acts on the metal surface are blocked maximally by the amino functional group of isatin rings. These inhibitors are mixed-type inhibitors as they retard both anodic and cathodic Tafel reactions. In future research, the isatin rings would be modified with the carbo dots, polymers, nanocarriers, ionic liquids, and surfactants, which would be dominant in corrosion inhibition analysis. © 2023 Elsevier B.V.
KW - Adsorption isotherm
KW - Computational study
KW - Corrosion inhibition
KW - Electrochemical analysis
KW - Isatin
KW - Surface analysis
KW - Aluminum alloys
KW - Aluminum corrosion
KW - Biocompatibility
KW - Copper alloys
KW - Copper corrosion
KW - Corrosion inhibitors
KW - Electrochemical corrosion
KW - Ionic liquids
KW - Organic compounds
KW - Aluminum-copper
KW - Computational studies
KW - Economical methods
KW - Heterocyclic compound
KW - Iron-aluminum
KW - Metallic material
KW - N-heterocyclic
U2 - 10.1016/j.molstruc.2023.136313
DO - 10.1016/j.molstruc.2023.136313
M3 - Article
SN - 0022-2860
VL - 1294
JO - J. Mol. Struct.
JF - J. Mol. Struct.
ER -