Growth and characterization of GaAsP top cells for high efficiency III-V/Si tandem PV

Timothy Milakovich, Rushabh Shah, Sabina Hadi, Mayank Bulsara, Ammar Nayfeh, Eugene Fitzgerald

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

8 Scopus citations

Abstract

We investigate the growth, microstructure and device characteristics of 1.71eV bandgap GaAs0.76P0.24 solar cells grown on Si substrates using SiyGe1-y graded buffers. Our optimized growth conditions suppress defect nucleation at the GaAsP/SiGe heterointerface and enable the demonstration of single junction solar cells with a threading dislocation density of 3.4×106 cm-2, a 3× reduction compared to reported GaAsxP1-x cells grown on Si. The solar cells have high open-circuit voltages (Voc) of 1.22 V, bandgap-voltage offset (Woc) of 0.48 V (representing a 45 mV reduction over prior art). The short-circuit current density (jSC) is 11 mA/cm2 and the fill factor (FF) 82%, under AM1.5G irradiance without an anti-reflection coating (ARC). Integration of an ARC would push these GaAs0.77P0.23 single junction solar cells to >15% efficiency, making them well suited to cascade with a Si solar cell for high efficiency tandem solar cells.

Original languageBritish English
Title of host publication2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015
PublisherInstitute of Electrical and Electronics Engineers Inc.
ISBN (Electronic)9781479979448
DOIs
StatePublished - 14 Dec 2015
Event42nd IEEE Photovoltaic Specialist Conference, PVSC 2015 - New Orleans, United States
Duration: 14 Jun 201519 Jun 2015

Publication series

Name2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015

Conference

Conference42nd IEEE Photovoltaic Specialist Conference, PVSC 2015
Country/TerritoryUnited States
CityNew Orleans
Period14/06/1519/06/15

Keywords

  • GaAsP
  • III-V on silicon
  • metamorphic materials
  • Silicon germanium multi-junction photovoltaic cells

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