Fluorination of graphite at high temperatures

Vinay Gupta; Tsuyoshi Nakajima; Yoshimi Ohzawa

doi:10.1135/cccc20021366

Fluorination of graphite at high temperatures

Vinay Gupta
, Tsuyoshi Nakajima
, Yoshimi Ohzawa

Physics

Aichi Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Graphite powder (57-74 μm) was fluorinated at 380°C for 1 h-2 weeks. The composition of the products ranged from CF_0.055 to CF_0.659. X-Ray diffractometry showed the formation of graphite fluoride, (C₂F)_n with a trace of C_χF phase with planar layers in addition to unreacted graphite which finally disappeared. Raman spectroscopy clearly revealed the existence of a fluorinated phase with planar layers with sp² structure.

Original language	British English
Pages (from-to)	1366-1372
Number of pages	7
Journal	Collection of Czechoslovak Chemical Communications
Volume	67
Issue number	9
DOIs	https://doi.org/10.1135/cccc20021366
State	Published - 1 Sep 2002

Keywords

Fluorination process
Fluorine
Graphite
Graphite fluoride
Raman spectra

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10.1135/cccc20021366

Cite this

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title = "Fluorination of graphite at high temperatures",

abstract = "Graphite powder (57-74 μm) was fluorinated at 380°C for 1 h-2 weeks. The composition of the products ranged from CF0.055 to CF0.659. X-Ray diffractometry showed the formation of graphite fluoride, (C2F)n with a trace of CχF phase with planar layers in addition to unreacted graphite which finally disappeared. Raman spectroscopy clearly revealed the existence of a fluorinated phase with planar layers with sp2 structure.",

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T1 - Fluorination of graphite at high temperatures

AU - Gupta, Vinay

AU - Nakajima, Tsuyoshi

AU - Ohzawa, Yoshimi

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N2 - Graphite powder (57-74 μm) was fluorinated at 380°C for 1 h-2 weeks. The composition of the products ranged from CF0.055 to CF0.659. X-Ray diffractometry showed the formation of graphite fluoride, (C2F)n with a trace of CχF phase with planar layers in addition to unreacted graphite which finally disappeared. Raman spectroscopy clearly revealed the existence of a fluorinated phase with planar layers with sp2 structure.

AB - Graphite powder (57-74 μm) was fluorinated at 380°C for 1 h-2 weeks. The composition of the products ranged from CF0.055 to CF0.659. X-Ray diffractometry showed the formation of graphite fluoride, (C2F)n with a trace of CχF phase with planar layers in addition to unreacted graphite which finally disappeared. Raman spectroscopy clearly revealed the existence of a fluorinated phase with planar layers with sp2 structure.

KW - Fluorination process

KW - Fluorine

KW - Graphite

KW - Graphite fluoride

KW - Raman spectra

UR - https://www.scopus.com/pages/publications/0036761939

U2 - 10.1135/cccc20021366

DO - 10.1135/cccc20021366

M3 - Article

AN - SCOPUS:0036761939

SN - 0010-0765

VL - 67

SP - 1366

EP - 1372

JO - Collection of Czechoslovak Chemical Communications

JF - Collection of Czechoslovak Chemical Communications

IS - 9

ER -

Fluorination of graphite at high temperatures

Abstract

Keywords

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