Facile Synthesis of Microstrip-Like Copper Phosphate Hydroxide Thin Films for Supercapacitor Applications

Sachin S. Pujari; Sujit A. Kadam; Yuan Ron Ma; Pranav K. Katkar; Supriya J. Marje; Suraj A. Khalate; Abhishek C. Lokhande; Umakant M. Patil

doi:10.1007/s11664-020-08095-w

Facile Synthesis of Microstrip-Like Copper Phosphate Hydroxide Thin Films for Supercapacitor Applications

Sachin S. Pujari
, Sujit A. Kadam
, Yuan Ron Ma
, Pranav K. Katkar
, Supriya J. Marje
, Suraj A. Khalate
, Abhishek C. Lokhande
, Umakant M. Patil

Mechanical & Nuclear Engineering

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

Abstract: Binder-free copper phosphate hydroxide [Cu₂(PO₄)(OH)] thin films have been prepared on stainless-steel (SS) substrates at 393 K via a facile hydrothermal method. X-ray diffraction analysis confirmed the formation of orthorhombic-structured copper phosphate hydroxide [Cu₂(PO₄)(OH)] thin films with uniform microstrip-like morphology and Brunauer–Emmett–Teller (BET) surface area of 5.26 m² g⁻¹. The electrochemical performance of the films depended on their thickness, with a maximum specific capacitance of 280 F g⁻¹ at a scan rate 5 mV s⁻¹ in 1 M KOH electrolyte. The [Cu₂(PO₄)(OH)] electrode delivered an energy density of 3.85 Wh kg⁻¹ and a power density of 264.70 W kg⁻¹ with excellent (91%) capacitive retention after 2000 cycles. This excellent electrochemical performance shows that such microstrip-like Cu₂(PO₄)(OH) thin films are promising electrodes for high-performance supercapacitors. Graphic Abstract: [Figure not available: see fulltext.].

Original language	British English
Pages (from-to)	3890-3901
Number of pages	12
Journal	Journal of Electronic Materials
Volume	49
Issue number	6
DOIs	https://doi.org/10.1007/s11664-020-08095-w
State	Published - 1 Jun 2020

Keywords

Copper phosphate hydroxide
hydrothermal method
microstrip
supercapacitor
thin film

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@article{816bcfdd1f4a4f9b892da88d8877faf3,

title = "Facile Synthesis of Microstrip-Like Copper Phosphate Hydroxide Thin Films for Supercapacitor Applications",

abstract = "Abstract: Binder-free copper phosphate hydroxide [Cu2(PO4)(OH)] thin films have been prepared on stainless-steel (SS) substrates at 393 K via a facile hydrothermal method. X-ray diffraction analysis confirmed the formation of orthorhombic-structured copper phosphate hydroxide [Cu2(PO4)(OH)] thin films with uniform microstrip-like morphology and Brunauer–Emmett–Teller (BET) surface area of 5.26 m2 g−1. The electrochemical performance of the films depended on their thickness, with a maximum specific capacitance of 280 F g−1 at a scan rate 5 mV s−1 in 1 M KOH electrolyte. The [Cu2(PO4)(OH)] electrode delivered an energy density of 3.85 Wh kg−1 and a power density of 264.70 W kg−1 with excellent (91\%) capacitive retention after 2000 cycles. This excellent electrochemical performance shows that such microstrip-like Cu2(PO4)(OH) thin films are promising electrodes for high-performance supercapacitors. Graphic Abstract: [Figure not available: see fulltext.].",

keywords = "Copper phosphate hydroxide, hydrothermal method, microstrip, supercapacitor, thin film",

author = "Pujari, \{Sachin S.\} and Kadam, \{Sujit A.\} and Ma, \{Yuan Ron\} and Katkar, \{Pranav K.\} and Marje, \{Supriya J.\} and Khalate, \{Suraj A.\} and Lokhande, \{Abhishek C.\} and Patil, \{Umakant M.\}",

note = "Publisher Copyright: {\textcopyright} 2020, The Minerals, Metals \& Materials Society.",

year = "2020",

month = jun,

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doi = "10.1007/s11664-020-08095-w",

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T1 - Facile Synthesis of Microstrip-Like Copper Phosphate Hydroxide Thin Films for Supercapacitor Applications

AU - Pujari, Sachin S.

AU - Kadam, Sujit A.

AU - Ma, Yuan Ron

AU - Katkar, Pranav K.

AU - Marje, Supriya J.

AU - Khalate, Suraj A.

AU - Lokhande, Abhishek C.

AU - Patil, Umakant M.

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Abstract: Binder-free copper phosphate hydroxide [Cu2(PO4)(OH)] thin films have been prepared on stainless-steel (SS) substrates at 393 K via a facile hydrothermal method. X-ray diffraction analysis confirmed the formation of orthorhombic-structured copper phosphate hydroxide [Cu2(PO4)(OH)] thin films with uniform microstrip-like morphology and Brunauer–Emmett–Teller (BET) surface area of 5.26 m2 g−1. The electrochemical performance of the films depended on their thickness, with a maximum specific capacitance of 280 F g−1 at a scan rate 5 mV s−1 in 1 M KOH electrolyte. The [Cu2(PO4)(OH)] electrode delivered an energy density of 3.85 Wh kg−1 and a power density of 264.70 W kg−1 with excellent (91%) capacitive retention after 2000 cycles. This excellent electrochemical performance shows that such microstrip-like Cu2(PO4)(OH) thin films are promising electrodes for high-performance supercapacitors. Graphic Abstract: [Figure not available: see fulltext.].

AB - Abstract: Binder-free copper phosphate hydroxide [Cu2(PO4)(OH)] thin films have been prepared on stainless-steel (SS) substrates at 393 K via a facile hydrothermal method. X-ray diffraction analysis confirmed the formation of orthorhombic-structured copper phosphate hydroxide [Cu2(PO4)(OH)] thin films with uniform microstrip-like morphology and Brunauer–Emmett–Teller (BET) surface area of 5.26 m2 g−1. The electrochemical performance of the films depended on their thickness, with a maximum specific capacitance of 280 F g−1 at a scan rate 5 mV s−1 in 1 M KOH electrolyte. The [Cu2(PO4)(OH)] electrode delivered an energy density of 3.85 Wh kg−1 and a power density of 264.70 W kg−1 with excellent (91%) capacitive retention after 2000 cycles. This excellent electrochemical performance shows that such microstrip-like Cu2(PO4)(OH) thin films are promising electrodes for high-performance supercapacitors. Graphic Abstract: [Figure not available: see fulltext.].

KW - Copper phosphate hydroxide

KW - hydrothermal method

KW - microstrip

KW - supercapacitor

KW - thin film

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DO - 10.1007/s11664-020-08095-w

M3 - Article

AN - SCOPUS:85083162321

SN - 0361-5235

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JO - Journal of Electronic Materials

JF - Journal of Electronic Materials

IS - 6

ER -

Facile Synthesis of Microstrip-Like Copper Phosphate Hydroxide Thin Films for Supercapacitor Applications

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