Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones

Victor Ceban; Jií Tauchman; Marta Meazza; Greg Gallagher; Mark E. Light; Ivana Gergelitsová; Jan Veselý; Ramon Rios

doi:10.1038/srep16886

Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones

Victor Ceban
, Jií Tauchman
, Marta Meazza
, Greg Gallagher
, Mark E. Light
, Ivana Gergelitsová
, Jan Veselý
, Ramon Rios

Chemistry

University of Southampton
Charles University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.

Original language	British English
Article number	16886
Journal	Scientific Reports
Volume	5
DOIs	https://doi.org/10.1038/srep16886
State	Published - 23 Nov 2015

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title = "Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones",

abstract = "The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.",

author = "Victor Ceban and Ji{\'i} Tauchman and Marta Meazza and Greg Gallagher and Light, \{Mark E.\} and Ivana Gergelitsov{\'a} and Jan Vesel{\'y} and Ramon Rios",

note = "Funding Information: V.C., M.M., G.G. and R.R. acknowledge the European Regional Development Fund (ERDF) for cofinancing the AI-CHEM -Chem project (No. 4061) through the INTERREG IV A France (Channel) - England cross-border cooperation Programme. J.V. thanks GAUK No. 427011. Publication is co-financed by the European Social Fund and the state budget of the Czech Republic (Project CZ.1.07/2.3.00/30.0022) This work was done under the auspices of COST Action CM0905 (ORCA).",

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doi = "10.1038/srep16886",

language = "British English",

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T1 - Expanding the scope of Metal-Free enantioselective allylic substitutions

T2 - Anthrones

AU - Ceban, Victor

AU - Tauchman, Jií

AU - Meazza, Marta

AU - Gallagher, Greg

AU - Light, Mark E.

AU - Gergelitsová, Ivana

AU - Veselý, Jan

AU - Rios, Ramon

N1 - Funding Information: V.C., M.M., G.G. and R.R. acknowledge the European Regional Development Fund (ERDF) for cofinancing the AI-CHEM -Chem project (No. 4061) through the INTERREG IV A France (Channel) - England cross-border cooperation Programme. J.V. thanks GAUK No. 427011. Publication is co-financed by the European Social Fund and the state budget of the Czech Republic (Project CZ.1.07/2.3.00/30.0022) This work was done under the auspices of COST Action CM0905 (ORCA).

PY - 2015/11/23

Y1 - 2015/11/23

N2 - The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.

AB - The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.

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SN - 2045-2322

VL - 5

JO - Scientific Reports

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ER -

Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones

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