Evaluation of the solvent structural effect upon the vapor –liquid equilibrium of [C4C1im][Cl] + alcohols

Naima Chouireb; Imran Khan; Emanuel A. Crespo; Mariana B. Oliveira; Fèlix Llovell; Lourdes F. Vega; O. Tafat-Igoudjilene; A. Ait Kaci; Luís M.N.B.F. Santos; Pedro J. Carvalho; João A.P. Coutinho

doi:10.1016/j.fluid.2017.02.016

Evaluation of the solvent structural effect upon the vapor –liquid equilibrium of [C₄C₁im][Cl] + alcohols

Naima Chouireb
, Imran Khan
, Emanuel A. Crespo
, Mariana B. Oliveira
, Fèlix Llovell
, Lourdes F. Vega
, O. Tafat-Igoudjilene
, A. Ait Kaci
, Luís M.N.B.F. Santos
, Pedro J. Carvalho
, João A.P. Coutinho

Chemical and Petroleum Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A systematic isobaric vapor-liquid equilibrium (VLE) study of seven binary mixtures of 1-butyl-3-methylimidazolium chloride, [C₄C₁im][Cl], and methanol, propan-1-ol, propan-2-ol, butan-1-ol, butan-2-ol, tert-butanol (2-methylpropan-2-ol), iso-butanol (2-methylpropan-1-ol) and pentan-1-ol, was carried out at three different system pressures (0.1, 0.07 and 0.05 MPa). Activity coefficients were estimated from the boiling temperatures of the binary mixtures. soft-SAFT equation of state was used to describe the experimental VLE data and all together, allowed to infer and understand the effect of the alcohol alkyl chain length and structural isomerism on the molecular interactions between the IL and the alcohols.

Original language	British English
Pages (from-to)	36-44
Number of pages	9
Journal	Fluid Phase Equilibria
Volume	440
DOIs	https://doi.org/10.1016/j.fluid.2017.02.016
State	Published - 25 May 2017

Keywords

1-Butyl-3-methylimidazolium chloride
Activity coefficients
Alcohols
Alkyl chain length
Binary mixtures
Isomers
Soft –SAFT
Vapor-liquid equilibrium

Access to Document

10.1016/j.fluid.2017.02.016

OpenUrl availability

Full text

Cite this

Chouireb, N., Khan, I., Crespo, E. A., Oliveira, M. B., Llovell, F., Vega, L. F., Tafat-Igoudjilene, O., Kaci, A. A., Santos, L. M. N. B. F., Carvalho, P. J., & Coutinho, J. A. P. (2017). Evaluation of the solvent structural effect upon the vapor –liquid equilibrium of [C₄C₁im][Cl] + alcohols. Fluid Phase Equilibria, 440, 36-44. https://doi.org/10.1016/j.fluid.2017.02.016

@article{bab03276920b424ca4624dddf00b06e8,

title = "Evaluation of the solvent structural effect upon the vapor –liquid equilibrium of [C4C1im][Cl] + alcohols",

abstract = "A systematic isobaric vapor-liquid equilibrium (VLE) study of seven binary mixtures of 1-butyl-3-methylimidazolium chloride, [C4C1im][Cl], and methanol, propan-1-ol, propan-2-ol, butan-1-ol, butan-2-ol, tert-butanol (2-methylpropan-2-ol), iso-butanol (2-methylpropan-1-ol) and pentan-1-ol, was carried out at three different system pressures (0.1, 0.07 and 0.05 MPa). Activity coefficients were estimated from the boiling temperatures of the binary mixtures. soft-SAFT equation of state was used to describe the experimental VLE data and all together, allowed to infer and understand the effect of the alcohol alkyl chain length and structural isomerism on the molecular interactions between the IL and the alcohols.",

keywords = "1-Butyl-3-methylimidazolium chloride, Activity coefficients, Alcohols, Alkyl chain length, Binary mixtures, Isomers, Soft –SAFT, Vapor-liquid equilibrium",

author = "Naima Chouireb and Imran Khan and Crespo, \{Emanuel A.\} and Oliveira, \{Mariana B.\} and F{\`e}lix Llovell and Vega, \{Lourdes F.\} and O. Tafat-Igoudjilene and Kaci, \{A. Ait\} and Santos, \{Lu{\'i}s M.N.B.F.\} and Carvalho, \{Pedro J.\} and Coutinho, \{Jo{\~a}o A.P.\}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = may,

day = "25",

doi = "10.1016/j.fluid.2017.02.016",

language = "British English",

volume = "440",

pages = "36--44",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Evaluation of the solvent structural effect upon the vapor –liquid equilibrium of [C4C1im][Cl] + alcohols

AU - Chouireb, Naima

AU - Khan, Imran

AU - Crespo, Emanuel A.

AU - Oliveira, Mariana B.

AU - Llovell, Fèlix

AU - Vega, Lourdes F.

AU - Tafat-Igoudjilene, O.

AU - Kaci, A. Ait

AU - Santos, Luís M.N.B.F.

AU - Carvalho, Pedro J.

AU - Coutinho, João A.P.

PY - 2017/5/25

Y1 - 2017/5/25

N2 - A systematic isobaric vapor-liquid equilibrium (VLE) study of seven binary mixtures of 1-butyl-3-methylimidazolium chloride, [C4C1im][Cl], and methanol, propan-1-ol, propan-2-ol, butan-1-ol, butan-2-ol, tert-butanol (2-methylpropan-2-ol), iso-butanol (2-methylpropan-1-ol) and pentan-1-ol, was carried out at three different system pressures (0.1, 0.07 and 0.05 MPa). Activity coefficients were estimated from the boiling temperatures of the binary mixtures. soft-SAFT equation of state was used to describe the experimental VLE data and all together, allowed to infer and understand the effect of the alcohol alkyl chain length and structural isomerism on the molecular interactions between the IL and the alcohols.

AB - A systematic isobaric vapor-liquid equilibrium (VLE) study of seven binary mixtures of 1-butyl-3-methylimidazolium chloride, [C4C1im][Cl], and methanol, propan-1-ol, propan-2-ol, butan-1-ol, butan-2-ol, tert-butanol (2-methylpropan-2-ol), iso-butanol (2-methylpropan-1-ol) and pentan-1-ol, was carried out at three different system pressures (0.1, 0.07 and 0.05 MPa). Activity coefficients were estimated from the boiling temperatures of the binary mixtures. soft-SAFT equation of state was used to describe the experimental VLE data and all together, allowed to infer and understand the effect of the alcohol alkyl chain length and structural isomerism on the molecular interactions between the IL and the alcohols.

KW - 1-Butyl-3-methylimidazolium chloride

KW - Activity coefficients

KW - Alcohols

KW - Alkyl chain length

KW - Binary mixtures

KW - Isomers

KW - Soft –SAFT

KW - Vapor-liquid equilibrium

UR - https://www.scopus.com/pages/publications/85014514052

U2 - 10.1016/j.fluid.2017.02.016

DO - 10.1016/j.fluid.2017.02.016

M3 - Article

AN - SCOPUS:85014514052

SN - 0378-3812

VL - 440

SP - 36

EP - 44

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

ER -