Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates

Xavier Companyó; Guillem Valero; Victor Ceban; Teresa Calvet; Mercé Font-Bardía; Albert Moyano; Ramon Rios

doi:10.1039/c1ob06308a

Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates

Xavier Companyó, Guillem Valero, Victor Ceban, Teresa Calvet, Mercé Font-Bardía, Albert Moyano, Ramon Rios

Chemistry

Universitat de Barcelona

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with bis(phenylsulfonyl)methane is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and enantioselectivities.

Original language	British English
Pages (from-to)	7986-7989
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	9
Issue number	23
DOIs	https://doi.org/10.1039/c1ob06308a
State	Published - 7 Dec 2011

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10.1039/c1ob06308a

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title = "Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates",

abstract = "The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with bis(phenylsulfonyl)methane is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and enantioselectivities.",

author = "Xavier Company{\'o} and Guillem Valero and Victor Ceban and Teresa Calvet and Merc{\'e} Font-Bard{\'i}a and Albert Moyano and Ramon Rios",

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T1 - Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates

AU - Companyó, Xavier

AU - Valero, Guillem

AU - Ceban, Victor

AU - Calvet, Teresa

AU - Font-Bardía, Mercé

AU - Moyano, Albert

AU - Rios, Ramon

PY - 2011/12/7

Y1 - 2011/12/7

N2 - The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with bis(phenylsulfonyl)methane is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and enantioselectivities.

AB - The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with bis(phenylsulfonyl)methane is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and enantioselectivities.

UR - http://www.scopus.com/inward/record.url?scp=81255128881&partnerID=8YFLogxK

U2 - 10.1039/c1ob06308a

DO - 10.1039/c1ob06308a

M3 - Article

AN - SCOPUS:81255128881

SN - 1477-0520

VL - 9

SP - 7986

EP - 7989

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 23

ER -

Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates

Abstract

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