Electrochemical generation of superoxide ion in ionic liquid 1-(3-Methoxypropyl)-1-Methylpiperidinium Bis (Trifluoromethylsulfonyl) Imide

Maan Hayyan; Farouq S. Mjalli; Mohd Ali Hashim; Inas M. Alnashef

doi:10.1088/1757-899X/17/1/012028

Electrochemical generation of superoxide ion in ionic liquid 1-(3-Methoxypropyl)-1-Methylpiperidinium Bis (Trifluoromethylsulfonyl) Imide

Maan Hayyan, Farouq S. Mjalli, Mohd Ali Hashim, Inas M. Alnashef

Chemical and Petroleum Engineering

University of Malaya

Research output: Contribution to journal › Conference article › peer-review

8 Scopus citations

Abstract

In this work, the superoxide ion was generated and analysed electrochemically using cyclic voltammetry (CV) techniques from oxygen dissolved in a room-temperature ionic liquid, 1-(3-methoxypropyl)-1-methylpiperidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications. To the best of our knowledge, this is the first time a piperidinium based IL has been used for the electrochemical generation of O₂.

Original language	British English
Article number	012028
Journal	IOP Conference Series: Materials Science and Engineering
Volume	17
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/17/1/012028
State	Published - 2011
Event	Conference on Advanced Materials and Nanotechnology, CAMAN 2009 - Kuala Lumpur, Malaysia Duration: 3 Nov 2009 → 5 Nov 2009

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title = "Electrochemical generation of superoxide ion in ionic liquid 1-(3-Methoxypropyl)-1-Methylpiperidinium Bis (Trifluoromethylsulfonyl) Imide",

abstract = "In this work, the superoxide ion was generated and analysed electrochemically using cyclic voltammetry (CV) techniques from oxygen dissolved in a room-temperature ionic liquid, 1-(3-methoxypropyl)-1-methylpiperidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications. To the best of our knowledge, this is the first time a piperidinium based IL has been used for the electrochemical generation of O2.",

author = "Maan Hayyan and Mjalli, {Farouq S.} and Hashim, {Mohd Ali} and Alnashef, {Inas M.}",

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T1 - Electrochemical generation of superoxide ion in ionic liquid 1-(3-Methoxypropyl)-1-Methylpiperidinium Bis (Trifluoromethylsulfonyl) Imide

AU - Hayyan, Maan

AU - Mjalli, Farouq S.

AU - Hashim, Mohd Ali

AU - Alnashef, Inas M.

PY - 2011

Y1 - 2011

N2 - In this work, the superoxide ion was generated and analysed electrochemically using cyclic voltammetry (CV) techniques from oxygen dissolved in a room-temperature ionic liquid, 1-(3-methoxypropyl)-1-methylpiperidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications. To the best of our knowledge, this is the first time a piperidinium based IL has been used for the electrochemical generation of O2.

AB - In this work, the superoxide ion was generated and analysed electrochemically using cyclic voltammetry (CV) techniques from oxygen dissolved in a room-temperature ionic liquid, 1-(3-methoxypropyl)-1-methylpiperidinium bis (trifluoromethylsulfonyl) imide, at atmospheric pressure. It was found that the generated superoxide ion was stable which indicates its possible use for further useful applications. To the best of our knowledge, this is the first time a piperidinium based IL has been used for the electrochemical generation of O2.

UR - http://www.scopus.com/inward/record.url?scp=79952681370&partnerID=8YFLogxK

U2 - 10.1088/1757-899X/17/1/012028

DO - 10.1088/1757-899X/17/1/012028

M3 - Conference article

AN - SCOPUS:79952681370

SN - 1757-8981

VL - 17

JO - IOP Conference Series: Materials Science and Engineering

JF - IOP Conference Series: Materials Science and Engineering

IS - 1

M1 - 012028

T2 - Conference on Advanced Materials and Nanotechnology, CAMAN 2009

Y2 - 3 November 2009 through 5 November 2009

ER -

Electrochemical generation of superoxide ion in ionic liquid 1-(3-Methoxypropyl)-1-Methylpiperidinium Bis (Trifluoromethylsulfonyl) Imide

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