Effect of iodine filler on photoisomerization kinetics of photo‐switchable thin films based on peo‐bdk‐mr

Qais M. Al‐bataineh; A. A. Ahmad; A. M. Alsaad; I. A. Qattan; Ihsan A. Aljarrah; Ahmad D. Telfah

doi:10.3390/polym13050841

Effect of iodine filler on photoisomerization kinetics of photo‐switchable thin films based on peo‐bdk‐mr

Qais M. Al‐bataineh
, A. A. Ahmad
, A. M. Alsaad
, I. A. Qattan
, Ihsan A. Aljarrah
, Ahmad D. Telfah

Physics

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

We report the effect of an iodine filler on photoisomerization kinetics of photo‐switchable PEO‐BDK‐MR thin films. The kinetics of photoisomerization and time progression of PEO‐BDK‐ MR/I2 nanocomposite thin films are investigated using UV‐Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO‐BDK‐MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO‐BDK‐MR)/I2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.

Original language	British English
Article number	841
Journal	Polymers
Volume	13
Issue number	5
DOIs	https://doi.org/10.3390/polym13050841
State	Published - 1 Mar 2021

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Benzyl Dimethyl Ketal (BDK)
Complex composite thin films
Iodine (I2)
Methyl‐Red (MR)
Molecular solar thermal energy storage media
Photoisomerization processes
Polyethylene Oxide (PEO)

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title = "Effect of iodine filler on photoisomerization kinetics of photo‐switchable thin films based on peo‐bdk‐mr",

abstract = "We report the effect of an iodine filler on photoisomerization kinetics of photo‐switchable PEO‐BDK‐MR thin films. The kinetics of photoisomerization and time progression of PEO‐BDK‐ MR/I2 nanocomposite thin films are investigated using UV‐Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO‐BDK‐MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO‐BDK‐MR)/I2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.",

keywords = "Benzyl Dimethyl Ketal (BDK), Complex composite thin films, Iodine (I2), Methyl‐Red (MR), Molecular solar thermal energy storage media, Photoisomerization processes, Polyethylene Oxide (PEO)",

author = "Al‐bataineh, \{Qais M.\} and Ahmad, \{A. A.\} and Alsaad, \{A. M.\} and Qattan, \{I. A.\} and Aljarrah, \{Ihsan A.\} and Telfah, \{Ahmad D.\}",

note = "Funding Information: The authors would like to acknowledge Jordan University of Science and Technology (JUST), Jordan. Our thanks are extended to Mohammad‐Ali H. Al‐Akhras for allowing our members to use biomedical laboratories. Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = mar,

day = "1",

doi = "10.3390/polym13050841",

language = "British English",

volume = "13",

journal = "Polymers",

issn = "2073-4360",

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TY - JOUR

T1 - Effect of iodine filler on photoisomerization kinetics of photo‐switchable thin films based on peo‐bdk‐mr

AU - Al‐bataineh, Qais M.

AU - Ahmad, A. A.

AU - Alsaad, A. M.

AU - Qattan, I. A.

AU - Aljarrah, Ihsan A.

AU - Telfah, Ahmad D.

N1 - Funding Information: The authors would like to acknowledge Jordan University of Science and Technology (JUST), Jordan. Our thanks are extended to Mohammad‐Ali H. Al‐Akhras for allowing our members to use biomedical laboratories. Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2021/3/1

Y1 - 2021/3/1

N2 - We report the effect of an iodine filler on photoisomerization kinetics of photo‐switchable PEO‐BDK‐MR thin films. The kinetics of photoisomerization and time progression of PEO‐BDK‐ MR/I2 nanocomposite thin films are investigated using UV‐Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO‐BDK‐MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO‐BDK‐MR)/I2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.

AB - We report the effect of an iodine filler on photoisomerization kinetics of photo‐switchable PEO‐BDK‐MR thin films. The kinetics of photoisomerization and time progression of PEO‐BDK‐ MR/I2 nanocomposite thin films are investigated using UV‐Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO‐BDK‐MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO‐BDK‐MR)/I2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.

KW - Benzyl Dimethyl Ketal (BDK)

KW - Complex composite thin films

KW - Iodine (I2)

KW - Methyl‐Red (MR)

KW - Molecular solar thermal energy storage media

KW - Photoisomerization processes

KW - Polyethylene Oxide (PEO)

UR - https://www.scopus.com/pages/publications/85102900803

U2 - 10.3390/polym13050841

DO - 10.3390/polym13050841

M3 - Article

AN - SCOPUS:85102900803

SN - 2073-4360

VL - 13

JO - Polymers

JF - Polymers

IS - 5

M1 - 841

ER -

Effect of iodine filler on photoisomerization kinetics of photo‐switchable thin films based on peo‐bdk‐mr

Abstract

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Keywords

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