Deposition and characterization of PEDOT/ZnO layers onto PET substrates

M. Garganourakis, S. Logothetidis, C. Pitsalidis, D. Georgiou, S. Kassavetis, A. Laskarakis

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

ZnO thin films of different thicknesses were deposited by pulsed direct-current magnetron sputtering onto poly(ethylene terephthalate) (PET) substrates and afterwards poly 3, 4-ethylenedioxythiophene:polystyrenesulfonate (PEDOT:PSS) was spin-coated onto the ZnO film. Spectroscopic ellipsometry in the Vis-fUV energy range (1.5-6.5 eV), X-ray diffraction and atomic force microscopy were used to reveal the properties of the deposited films. The size of crystallites increased from 5.1 to 7.4 nm, whereas the crystallinity of the ZnO films has been improved. The influence of different ZnO thickness on the optical properties of the PEDOT:PSS layer was studied as well. As the thickness of ZnO films increased, the surface roughness increased but the energy gap decreased after a critical thickness. Concerning the consequences to the PEDOT:PSS optical properties, no major changes occurred in the transition energies.

Original languageBritish English
Pages (from-to)6409-6413
Number of pages5
JournalThin Solid Films
Volume517
Issue number23
DOIs
StatePublished - 1 Oct 2009

Keywords

  • Atomic force microscopy
  • Magnetron sputtering
  • Optical parameters
  • PEDOT:PSS
  • Spectroscopic ellipsometry
  • X-ray diffraction
  • ZnO

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