Date palm biochar application to remove binary mixtures of Atenolol, Ibuprofen and Sulfamethoxazole from aqueous solution: Experimental and statistical physics modeling

J.F. Shaheen; Y.H. Fseha; B. Sizirici

doi:10.1016/j.biteb.2023.101619

Date palm biochar application to remove binary mixtures of Atenolol, Ibuprofen and Sulfamethoxazole from aqueous solution: Experimental and statistical physics modeling

J.F. Shaheen, Y.H. Fseha, B. Sizirici

Civil & Environmental Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Date palm-derived biochar (DPF600) was utilized to remove and adsorb commonly occurring pharmaceuticals such as atenolol (ATE), sulfamethoxazole (SMX), and ibuprofen (IBP) as binary solutes. Factors such as pH, concentrations, dosage and contact time were varied and optimal conditions were determined. The binary mixtures ATE+IBP, ATE+SMX, and IBP + SMX best fit the Freundlich and pseudo-second-order models. From the competitive monolayer model, it was observed that SMX preferentially adsorbed onto DPF600 followed by IBP and ATE. Calculated adsorption energies for all binary mixtures were

Original language	British English
Article number	101619
Journal	Bioresour. Technol. Rep.
Volume	24
DOIs	https://doi.org/10.1016/j.biteb.2023.101619
State	Published - Dec 2023

Keywords

Adsorption energy
Competitive monolayer model
Pharmaceuticals
Physisorption
Regeneration
Synergistic effect
Binary mixtures
Chemical stability
Hydrogen bonds
Hydrophobicity
Statistical Physics
Adsorption energies
Atenolol
Biochar
Date palm
Experimental physics
Statistical physics
Sulfamethoxazole
Monolayers
adsorbent
atenolol
carbon
charcoal
functional group
ibuprofen
sulfamethoxazole
adsorption kinetics
aqueous solution
Article
Brunauer Emmett Teller method
chemisorption
complex formation
concentration (parameter)
contact time
controlled study
date (fruit)
desorption
energy dispersive X ray spectroscopy
Fourier transform infrared spectroscopy
hydrogen bond
hydrophobicity
molecular weight
pH
physisorption
pore size
pore volume
reduction (chemistry)
scanning electron microscopy
solute
static electricity
surface area
surface charge
surface property
thermodynamics
waste component removal
waste water management
X ray diffraction

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.biteb.2023.101619

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85174931372&doi=10.1016%2fj.biteb.2023.101619&partnerID=40&md5=a4be57ede57076c2e7a8876f117309f8

Cite this

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title = "Date palm biochar application to remove binary mixtures of Atenolol, Ibuprofen and Sulfamethoxazole from aqueous solution: Experimental and statistical physics modeling",

abstract = "Date palm-derived biochar (DPF600) was utilized to remove and adsorb commonly occurring pharmaceuticals such as atenolol (ATE), sulfamethoxazole (SMX), and ibuprofen (IBP) as binary solutes. Factors such as pH, concentrations, dosage and contact time were varied and optimal conditions were determined. The binary mixtures ATE+IBP, ATE+SMX, and IBP + SMX best fit the Freundlich and pseudo-second-order models. From the competitive monolayer model, it was observed that SMX preferentially adsorbed onto DPF600 followed by IBP and ATE. Calculated adsorption energies for all binary mixtures were ",

keywords = "Adsorption energy, Competitive monolayer model, Pharmaceuticals, Physisorption, Regeneration, Synergistic effect, Binary mixtures, Chemical stability, Hydrogen bonds, Hydrophobicity, Statistical Physics, Adsorption energies, Atenolol, Biochar, Date palm, Experimental physics, Statistical physics, Sulfamethoxazole, Monolayers, adsorbent, atenolol, carbon, charcoal, functional group, ibuprofen, sulfamethoxazole, adsorption kinetics, aqueous solution, Article, Brunauer Emmett Teller method, chemisorption, complex formation, concentration (parameter), contact time, controlled study, date (fruit), desorption, energy dispersive X ray spectroscopy, Fourier transform infrared spectroscopy, hydrogen bond, hydrophobicity, molecular weight, pH, physisorption, pore size, pore volume, reduction (chemistry), scanning electron microscopy, solute, static electricity, surface area, surface charge, surface property, thermodynamics, waste component removal, waste water management, X ray diffraction",

author = "J.F. Shaheen and Y.H. Fseha and B. Sizirici",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

month = dec,

doi = "10.1016/j.biteb.2023.101619",

language = "British English",

volume = "24",

journal = "Bioresour. Technol. Rep.",

issn = "2589-014X",

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TY - JOUR

T1 - Date palm biochar application to remove binary mixtures of Atenolol, Ibuprofen and Sulfamethoxazole from aqueous solution

T2 - Experimental and statistical physics modeling

AU - Shaheen, J.F.

AU - Fseha, Y.H.

AU - Sizirici, B.

PY - 2023/12

Y1 - 2023/12

N2 - Date palm-derived biochar (DPF600) was utilized to remove and adsorb commonly occurring pharmaceuticals such as atenolol (ATE), sulfamethoxazole (SMX), and ibuprofen (IBP) as binary solutes. Factors such as pH, concentrations, dosage and contact time were varied and optimal conditions were determined. The binary mixtures ATE+IBP, ATE+SMX, and IBP + SMX best fit the Freundlich and pseudo-second-order models. From the competitive monolayer model, it was observed that SMX preferentially adsorbed onto DPF600 followed by IBP and ATE. Calculated adsorption energies for all binary mixtures were

AB - Date palm-derived biochar (DPF600) was utilized to remove and adsorb commonly occurring pharmaceuticals such as atenolol (ATE), sulfamethoxazole (SMX), and ibuprofen (IBP) as binary solutes. Factors such as pH, concentrations, dosage and contact time were varied and optimal conditions were determined. The binary mixtures ATE+IBP, ATE+SMX, and IBP + SMX best fit the Freundlich and pseudo-second-order models. From the competitive monolayer model, it was observed that SMX preferentially adsorbed onto DPF600 followed by IBP and ATE. Calculated adsorption energies for all binary mixtures were

KW - Adsorption energy

KW - Competitive monolayer model

KW - Pharmaceuticals

KW - Physisorption

KW - Regeneration

KW - Synergistic effect

KW - Binary mixtures

KW - Chemical stability

KW - Hydrogen bonds

KW - Hydrophobicity

KW - Statistical Physics

KW - Adsorption energies

KW - Atenolol

KW - Biochar

KW - Date palm

KW - Experimental physics

KW - Statistical physics

KW - Sulfamethoxazole

KW - Monolayers

KW - adsorbent

KW - atenolol

KW - carbon

KW - charcoal

KW - functional group

KW - ibuprofen

KW - sulfamethoxazole

KW - adsorption kinetics

KW - aqueous solution

KW - Article

KW - Brunauer Emmett Teller method

KW - chemisorption

KW - complex formation

KW - concentration (parameter)

KW - contact time

KW - controlled study

KW - date (fruit)

KW - desorption

KW - energy dispersive X ray spectroscopy

KW - Fourier transform infrared spectroscopy

KW - hydrogen bond

KW - hydrophobicity

KW - molecular weight

KW - pH

KW - physisorption

KW - pore size

KW - pore volume

KW - reduction (chemistry)

KW - scanning electron microscopy

KW - solute

KW - static electricity

KW - surface area

KW - surface charge

KW - surface property

KW - thermodynamics

KW - waste component removal

KW - waste water management

KW - X ray diffraction

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U2 - 10.1016/j.biteb.2023.101619

DO - 10.1016/j.biteb.2023.101619

M3 - Article

SN - 2589-014X

VL - 24

JO - Bioresour. Technol. Rep.

JF - Bioresour. Technol. Rep.

M1 - 101619

ER -

Date palm biochar application to remove binary mixtures of Atenolol, Ibuprofen and Sulfamethoxazole from aqueous solution: Experimental and statistical physics modeling

Abstract

Keywords

UN SDGs

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