Construction and characterization of a solution-filled external pressure balanced reference electrode

Tirdad Nickchi; Akram Alfantazi

doi:10.1016/j.corsci.2012.05.029

Construction and characterization of a solution-filled external pressure balanced reference electrode

Tirdad Nickchi, Akram Alfantazi

Chemical and Petroleum Engineering

The University of British Columbia

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

This paper aims at the details of construction and characterization of a solution-filled reference electrode. Using heat transfer analysis, the temperature profiles in the heat exchanger region of the reference electrode were obtained. Using these profiles, and available data on Soret coefficients, the thermal liquid junction potential was calculated as a maximum of 4.74. mV at the initial temperature of 473. K. The calculations for liquid junction potential and IR drop were also performed. Theoretical calculations of electrode potential were used to validate the calculations.

Original language	British English
Pages (from-to)	174-181
Number of pages	8
Journal	Corrosion Science
Volume	63
DOIs	https://doi.org/10.1016/j.corsci.2012.05.029
State	Published - Oct 2012

Keywords

B. Electrochemical calculation
B. Modelling studies
C. Potential measurements

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10.1016/j.corsci.2012.05.029

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title = "Construction and characterization of a solution-filled external pressure balanced reference electrode",

abstract = "This paper aims at the details of construction and characterization of a solution-filled reference electrode. Using heat transfer analysis, the temperature profiles in the heat exchanger region of the reference electrode were obtained. Using these profiles, and available data on Soret coefficients, the thermal liquid junction potential was calculated as a maximum of 4.74. mV at the initial temperature of 473. K. The calculations for liquid junction potential and IR drop were also performed. Theoretical calculations of electrode potential were used to validate the calculations.",

keywords = "B. Electrochemical calculation, B. Modelling studies, C. Potential measurements",

author = "Tirdad Nickchi and Akram Alfantazi",

note = "Funding Information: Financial support for this work was provided by The Natural Sciences and Engineering Research Council of Canada (NSERC) and The Natural Resources Canada (NRCan) Office of Energy Research and Development, in collaboration with Atomic Energy Canada Limited (AECL) through the NSERC/NRCan/AECL Generation IV Energy Technologies Program. We acknowledge the technical input and discussion in many aspects of this work with Professor Edouard Asselin.",

year = "2012",

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doi = "10.1016/j.corsci.2012.05.029",

language = "British English",

volume = "63",

pages = "174--181",

journal = "Corrosion Science",

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T1 - Construction and characterization of a solution-filled external pressure balanced reference electrode

AU - Nickchi, Tirdad

AU - Alfantazi, Akram

N1 - Funding Information: Financial support for this work was provided by The Natural Sciences and Engineering Research Council of Canada (NSERC) and The Natural Resources Canada (NRCan) Office of Energy Research and Development, in collaboration with Atomic Energy Canada Limited (AECL) through the NSERC/NRCan/AECL Generation IV Energy Technologies Program. We acknowledge the technical input and discussion in many aspects of this work with Professor Edouard Asselin.

PY - 2012/10

Y1 - 2012/10

N2 - This paper aims at the details of construction and characterization of a solution-filled reference electrode. Using heat transfer analysis, the temperature profiles in the heat exchanger region of the reference electrode were obtained. Using these profiles, and available data on Soret coefficients, the thermal liquid junction potential was calculated as a maximum of 4.74. mV at the initial temperature of 473. K. The calculations for liquid junction potential and IR drop were also performed. Theoretical calculations of electrode potential were used to validate the calculations.

AB - This paper aims at the details of construction and characterization of a solution-filled reference electrode. Using heat transfer analysis, the temperature profiles in the heat exchanger region of the reference electrode were obtained. Using these profiles, and available data on Soret coefficients, the thermal liquid junction potential was calculated as a maximum of 4.74. mV at the initial temperature of 473. K. The calculations for liquid junction potential and IR drop were also performed. Theoretical calculations of electrode potential were used to validate the calculations.

KW - B. Electrochemical calculation

KW - B. Modelling studies

KW - C. Potential measurements

UR - http://www.scopus.com/inward/record.url?scp=84864313559&partnerID=8YFLogxK

U2 - 10.1016/j.corsci.2012.05.029

DO - 10.1016/j.corsci.2012.05.029

M3 - Article

AN - SCOPUS:84864313559

SN - 0010-938X

VL - 63

SP - 174

EP - 181

JO - Corrosion Science

JF - Corrosion Science

ER -

Construction and characterization of a solution-filled external pressure balanced reference electrode

Abstract

Keywords

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