Cellulose supported ruthenium nanoclusters as an efficient and recyclable catalytic system for benzene hydrogenation under mild conditions

R. R. Patel; J. M. Barad; S. U. Nandanwar; A. A. Dabbawala; M. Chakraborty; P. A. Parikh; H. C. Baja

doi:10.1134/S002315841502007X

Cellulose supported ruthenium nanoclusters as an efficient and recyclable catalytic system for benzene hydrogenation under mild conditions

R. R. Patel, J. M. Barad, S. U. Nandanwar, A. A. Dabbawala, M. Chakraborty, P. A. Parikh, H. C. Baja

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3 Scopus citations

Abstract

Ruthenium nanoclusters supported on biopolymer cellulose were prepared by chemical reduction technique and characterized by various experimental tools. The cellulose supported Ru catalyst effectively hydrogenates benzene under mild and solvent free conditions. The complete conversion of benzene to cyclohexane was achieved at 70°C and 2.0 MPa partial pressure of H₂ in 1 h. Effect of various parameters such as reaction temperature, H₂ partial pressure, metal loading and catalyst amount on hydrogenation of benzene was studied in detail. The catalyst was recovered from product and reused upto four times without significant loss in its catalytic activity.

Original language	British English
Pages (from-to)	173-180
Number of pages	8
Journal	Kinetics and Catalysis
Volume	56
Issue number	2
DOIs	https://doi.org/10.1134/S002315841502007X
State	Published - 1 Mar 2015

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title = "Cellulose supported ruthenium nanoclusters as an efficient and recyclable catalytic system for benzene hydrogenation under mild conditions",

abstract = "Ruthenium nanoclusters supported on biopolymer cellulose were prepared by chemical reduction technique and characterized by various experimental tools. The cellulose supported Ru catalyst effectively hydrogenates benzene under mild and solvent free conditions. The complete conversion of benzene to cyclohexane was achieved at 70°C and 2.0 MPa partial pressure of H2 in 1 h. Effect of various parameters such as reaction temperature, H2 partial pressure, metal loading and catalyst amount on hydrogenation of benzene was studied in detail. The catalyst was recovered from product and reused upto four times without significant loss in its catalytic activity.",

author = "Patel, {R. R.} and Barad, {J. M.} and Nandanwar, {S. U.} and Dabbawala, {A. A.} and M. Chakraborty and Parikh, {P. A.} and Baja, {H. C.}",

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T1 - Cellulose supported ruthenium nanoclusters as an efficient and recyclable catalytic system for benzene hydrogenation under mild conditions

AU - Patel, R. R.

AU - Barad, J. M.

AU - Nandanwar, S. U.

AU - Dabbawala, A. A.

AU - Chakraborty, M.

AU - Parikh, P. A.

AU - Baja, H. C.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - Ruthenium nanoclusters supported on biopolymer cellulose were prepared by chemical reduction technique and characterized by various experimental tools. The cellulose supported Ru catalyst effectively hydrogenates benzene under mild and solvent free conditions. The complete conversion of benzene to cyclohexane was achieved at 70°C and 2.0 MPa partial pressure of H2 in 1 h. Effect of various parameters such as reaction temperature, H2 partial pressure, metal loading and catalyst amount on hydrogenation of benzene was studied in detail. The catalyst was recovered from product and reused upto four times without significant loss in its catalytic activity.

AB - Ruthenium nanoclusters supported on biopolymer cellulose were prepared by chemical reduction technique and characterized by various experimental tools. The cellulose supported Ru catalyst effectively hydrogenates benzene under mild and solvent free conditions. The complete conversion of benzene to cyclohexane was achieved at 70°C and 2.0 MPa partial pressure of H2 in 1 h. Effect of various parameters such as reaction temperature, H2 partial pressure, metal loading and catalyst amount on hydrogenation of benzene was studied in detail. The catalyst was recovered from product and reused upto four times without significant loss in its catalytic activity.

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JF - Kinetics and Catalysis

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ER -

Cellulose supported ruthenium nanoclusters as an efficient and recyclable catalytic system for benzene hydrogenation under mild conditions

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